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Inspired by nature, a supramolecular biomimetic heterojunction (Zn\u2010TIPP\/CdS) photocatalyst was designed by mimicking chloroplasts. The coupling of the unique supramolecular cage structure of Zn\u2010TIPP with CdS in this heterojunction successfully simulates the comprehensive functions of stroma and grana in chloroplasts, achieving one of the highest ethanol production rates (138.9\u00a0\u00b5mol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , 93% selectivity) via artificial photosynthesis, which significantly surpasses most previously documented photocatalysts. Driven by the fast charge transfer efficiency in the biomimetic heterojunction, the spatial confinement and multisite catalytic effects of the supramolecular cage in Zn\u2010TIPP enable the cascade conversion of CO\n                    <jats:sub>2<\/jats:sub>\n                    into ethanol as revealed by in situ characterizations and theoretical calculations. The establishment of such redox heterojunction would promote the design of efficient photocatalysts for the generation of value\u2010added fuels through artificial photosynthetic overall reaction.\n                  <\/jats:p>","DOI":"10.1002\/anie.6078601","type":"journal-article","created":{"date-parts":[[2026,7,21]],"date-time":"2026-07-21T12:15:13Z","timestamp":1784636113000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Supramolecular Cage\u2010Based Heterojunction: Chloroplast Mimicked Artificial Photosynthesis for Efficient Ethanol Production"],"prefix":"10.1002","volume":"65","author":[{"given":"Jing\u2010Wen","family":"Shi","sequence":"first","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Carbon Dioxide Resource Utilization, School of Chemistry South China Normal University  Guangzhou P. R. 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