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However, a major challenge stems from intrinsic lattice distortion necessitated by its thermo\u2010deficient synthesis below 400\u00a0\u00b0C. This structural heterogeneity became uncontrollable during high\u2010temperature electrochemical cycling, resulting in severe polyhedral fracture and electrochemical decay. Herein, we achieve highly stable cycling of Na\n                    <jats:sub>2.5<\/jats:sub>\n                    Fe\n                    <jats:sub>1.75<\/jats:sub>\n                    (SO\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    cathode through a quasi\u2010perfect ordered crystal design that exploits dipole interactions between polar bonds with specific low\u2010frequency microwave (50\u00a0Hz). This enhanced ordering strengthens covalent Fe 3\n                    <jats:italic>d<\/jats:italic>\n                    \u2013O 2\n                    <jats:italic>p<\/jats:italic>\n                    hybridization, significantly mitigates crystalline defects and stress accumulation, thereby enabling redox reactions and polyhedral evolution to proceed reversibly during deep (de)sodiation. The quasi\u2010perfect ordering suppresses heterogeneous electrolyte reactions and preserves interfacial integrity throughout extended cycling. Consequently, the developed cathode exhibits remarkable cyclability at 4.5\u00a0V, exceeding 4000 cycles at 25\u00a0\u00b0C and nearly 400 cycles at 60\u00a0\u00b0C, further validated in pouch cells.\n                  <\/jats:p>","DOI":"10.1002\/anie.6097046","type":"journal-article","created":{"date-parts":[[2026,3,10]],"date-time":"2026-03-10T08:16:26Z","timestamp":1773130586000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Mitigating Lattice Distortion of Iron\u2010Sulfate Cathode via Quasi\u2010Perfect Ordered Motif for High\u2010Temperature Sodium\u2010Ion Batteries"],"prefix":"10.1002","volume":"65","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8071-0341","authenticated-orcid":false,"given":"Jiyu","family":"Zhang","sequence":"first","affiliation":[{"name":"College of Chemistry Zhengzhou University  Zhengzhou Henan 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