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Herein, we propose a donor\u2013acceptor (D\u2013A) synergetic interaction strategy to enable high\u2010performance ZIBs by employing thiophene\u2010rich covalent triazine frameworks (SCTF\u2010DCT) as an advanced I\n                    <jats:sub>2<\/jats:sub>\n                    host catalyst. The strong D\u2013A cooperative effect combined with a rich micro\u2010mesoporous structure not only optimizes the polyiodides adsorption but also enhances the conversion kinetics of I\n                    <jats:sub>2<\/jats:sub>\n                    species. Benefiting from the strong D\u2013A effect, the as\u2010assembled ZIBs with I\n                    <jats:sub>2<\/jats:sub>\n                    loaded SCTF\u2010DCT (I\n                    <jats:sub>2<\/jats:sub>\n                    @SCTF\u2010DCT) cathode demonstrate exceptional cycling life, exceeding 100,000 cycles with a minimal decay rate of only 0.000198% per cycle. In\/ex situ characterizations and theoretical calculations reveal the reversible redox mechanism of I\n                    <jats:sub>2<\/jats:sub>\n                    species and highlight the significance of the D\u2013A collaborative effect. This work elucidates the mechanisms of adsorption and catalytic conversion of I\n                    <jats:sub>2<\/jats:sub>\n                    species via a D\u2013A synergetic interaction strategy, providing a promising approach for designing advanced host catalysts for next\u2010generation ZIBs and other energy storage systems.\n                  <\/jats:p>","DOI":"10.1002\/anie.6120547","type":"journal-article","created":{"date-parts":[[2026,5,19]],"date-time":"2026-05-19T16:19:13Z","timestamp":1779207553000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Strong Donor\u2013Acceptor Effect Enables Efficient Polyiodides Confinement and Fast Redox Kinetics Toward Zinc\u2013Iodine Batteries"],"prefix":"10.1002","volume":"65","author":[{"given":"Yuliang","family":"Zhao","sequence":"first","affiliation":[{"name":"State Key Laboratory of Organic\u2010Inorganic Composites Beijing Advanced Innovation Center for Soft Matter Science and Engineering College of Chemical Engineering Beijing University of Chemical Technology  Beijing P. 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