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Here, we address this long\u2010standing challenge through spatial electronic engineering that enables dual\n                    <jats:italic>d\u2013p<\/jats:italic>\n                    orbital hybridization within a Pt\u2010based ternary alloy. The resulting PtGaGe catalyst exhibits exceptional alkaline ORR performance, achieving a mass activity of 1.79 A\u00b7mg\n                    <jats:sub>Pt<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    and a half\u2010wave potential of 0.90 V (vs. RHE)\u2014both surpassing commercial Pt\/C and most previously reported Pt\u2010based catalysts. When integrated into a ZAB, it reaches a peak power density of 207.6 mW\u00b7cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and maintains steady operation for over 200 h at 10 mA\u00b7cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , highlighting outstanding durability under practical operating conditions. Density functional theory (DFT) calculations reveal that dual\n                    <jats:italic>d\u2013p<\/jats:italic>\n                    hybridization induces spatial electron redistribution between Pt and Ga\/Ge sites, modulating the Pt\n                    <jats:italic>d<\/jats:italic>\n                    \u2010band center and facilitating O\u2500O bond activation while suppressing catalyst degradation. This synergistic electronic regulation simultaneously improves catalytic activity, stability, and Pt utilization efficiency. This work establishes a mechanistic paradigm for electronic\u2010structure engineering in high\u2010performance ORR electrocatalysts.\n                  <\/jats:p>","DOI":"10.1002\/anie.6156560","type":"journal-article","created":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T12:52:39Z","timestamp":1788439959000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Dual\n                    <i>d\u2013<\/i>\n                    <i>p<\/i>\n                    hybridization in Ternary PtGaGe Enables Concurrent Activity and Stability Enhancement for Alkaline Oxygen Reduction"],"prefix":"10.1002","volume":"65","author":[{"given":"Qian","family":"Zhang","sequence":"first","affiliation":[{"name":"College of Chemical Engineering Qingdao University of Science &amp; Technology Qingdao University of Science &amp; Technology  Qingdao 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Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao\u2010Dong","family":"Zhu","sequence":"additional","affiliation":[{"name":"College of Chemical Engineering Qingdao University of Science &amp; Technology Qingdao University of Science &amp; Technology  Qingdao China"},{"name":"State Key Laboratory of Advanced Optical Polymer and Manufacturing Technology Qingdao University of Science &amp; Technology  Qingdao 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