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Here we report a thermoresponsive biomass interphase that enables temperature\u2010adaptive zinc anodes through dynamic interfacial adsorption. Constructed from gelatin and sulfonated cellulose nanocrystals, the interphase undergoes reversible gel\u2010quasi\u2010liquid transitions within the operating temperature window of aqueous zinc batteries. At room temperature, the hydrogen\u2010bonded network homogenizes Zn\n                    <jats:sup>2+<\/jats:sup>\n                    flux and spatially confines deposition, thereby suppressing dendrite growth and corrosion. At elevated temperature, the interphase switches to a dynamic adsorption mode, in which reconfigured polymer chains expose zincophilic groups that promote Zn(002)\u2010preferred deposition and inhibit hydrogen evolution and by\u2010product formation. This thermally triggered switching mechanism enables symmetric cells to achieve stable cycling over 2000\u00a0h at 30\u00b0C and 730\u00a0h at 60\u00b0C. At 30\u00b0C, full cells with a V\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    cathode retain 90.53% of their initial capacity after 2000 cycles at 10C. At 60\u00b0C, the I\n                    <jats:sub>2<\/jats:sub>\n                    \u2010based full cell achieves 91.1% after 2500 cycles at 4C, and can even sustain 9600 cycles at 15C. Life\u2010cycle assessment further reveals reduced environmental impacts relative to conventional protective films. This work establishes a new interphase design paradigm offering a sustainable route toward high\u2010temperature\u2010stable batteries.\n                  <\/jats:p>","DOI":"10.1002\/anie.6160556","type":"journal-article","created":{"date-parts":[[2026,9,17]],"date-time":"2026-09-17T06:27:31Z","timestamp":1789626451000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Dynamic Interfacial Adsorption via a Thermoresponsive Biomass Interphase Enables Temperature\u2010Adaptive Zinc Anodes"],"prefix":"10.1002","author":[{"given":"Jin","family":"Yan","sequence":"first","affiliation":[{"name":"Beijing Key Laboratory of Environmental Science and Engineering School of Materials Science and Engineering, Beijing Institute of Technology  Beijing China"},{"name":"Shandong Key Laboratory of Advanced Chemical Energy Storage and Intelligent Safety Advanced Technology Research Institute Beijing Institute of Technology  Jinan 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Materials Science and Engineering, Beijing Institute of Technology  Beijing China"},{"name":"Shandong Key Laboratory of Advanced Chemical Energy Storage and Intelligent Safety Advanced Technology Research Institute Beijing Institute of Technology  Jinan China"},{"name":"Innovative Research Team in High\u2010Safety Energy Storage System and Smart Microgrids of Guangdong Province Beijing Institute of Technology  Zhuhai China"},{"name":"Collaborative Innovation Center of Electric Vehicles in Beijing  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8859-076X","authenticated-orcid":false,"given":"Li","family":"Li","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory of Environmental Science and Engineering School of Materials Science and Engineering, Beijing Institute of Technology  Beijing China"},{"name":"Shandong Key Laboratory of Advanced Chemical Energy Storage and Intelligent Safety Advanced Technology 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