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The conversion of CO\n                    <jats:sub>2<\/jats:sub>\n                    into ethylene glycol, an important chemical that is typically produced by thermo\u2010catalytic process, has not been achieved by photocatalysis or electrocatalysis. Herein, we demonstrate a microdroplet\u2010enhanced photocatalytic strategy with a Pd\u2010TiO\n                    <jats:sub>2<\/jats:sub>\n                    catalyst, which allows for efficient conversion of CO\n                    <jats:sub>2<\/jats:sub>\n                    into ethylene glycol with high selectivity. The electro\u2010sprayed microdroplets provide a high interfacial electric field that facilitates deep reduction of CO\n                    <jats:sub>2<\/jats:sub>\n                    into *CH\n                    <jats:sub>3<\/jats:sub>\n                    , as well as generation of reactive *OH intermediates to form CH\n                    <jats:sub>3<\/jats:sub>\n                    OH. The in situ formed CH\n                    <jats:sub>3<\/jats:sub>\n                    OH is further photo\u2010catalytically activated to cleave a C\u2212H bond to *CH\n                    <jats:sub>2<\/jats:sub>\n                    OH, followed by the C\u2212C coupling to produce ethylene glycol. Under 1\u2010sun illumination, the electro\u2010sprayed microdroplets and Pd\u2010TiO\n                    <jats:sub>2<\/jats:sub>\n                    catalyst exhibited a high CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010to\u2010ethylene glycol conversion rate of 2985\u00a0\u00b5mol L\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , which significantly outperformed those by only photocatalysis or only electro\u2010sprayed microdroplets, revealing the capability of combining multiple energy fields for tuning reaction pathways and advancing green synthesis.\n                  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