{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T14:03:01Z","timestamp":1790604181830,"version":"4.1.0"},"reference-count":107,"publisher":"Wiley","issue":"40","license":[{"start":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:00:00Z","timestamp":1785888000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:00:00Z","timestamp":1785888000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/100018992","name":"Fonds der Chemischen Industrie","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100018992","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,9,28]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>Z\u2010type ligands have been highly successful in stabilizing transition\u2010metal fragments in unique coordination geometries and in enabling novel reactivities. However, examples of the use of these ligands in stabilizing elusive main\u2010group metal fragments are scarce. In this study, we present the stabilization of aluminum (I) halides by an ambiphilic tris(phosphine)borane ligand. Unlocking unprecedented coordination chemistry at aluminum, the unique electronic structure of the novel compounds is analyzed in detail experimentally and computationally. Successful post\u2010functionalization via coordination of Lewis bases to the Al atom enables isolation of elusive Al cations with the metal in a low redox state. In addition, the Al(I)Br transfer onto 2,2\u2032\u2010bipyridine ligands is presented.<\/jats:p>","DOI":"10.1002\/anie.6333732","type":"journal-article","created":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T16:49:59Z","timestamp":1785948599000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Ambiphilic Ligand Stabilization of Aluminum(I) Fragments: Halides, Cations, and a Hydride"],"prefix":"10.1002","volume":"65","author":[{"ORCID":"https:\/\/orcid.org\/0009-0008-4506-0054","authenticated-orcid":false,"given":"Charlotte S. V.","family":"Wei\u00df","sequence":"first","affiliation":[{"name":"Anorganisch\u2010Chemisches Institut Ruprechts\u2010Karls\u2010Universit\u00e4t Heidelberg  Heidelberg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4602-7546","authenticated-orcid":false,"given":"Philipp","family":"Dabringhaus","sequence":"additional","affiliation":[{"name":"Anorganisch\u2010Chemisches Institut Ruprechts\u2010Karls\u2010Universit\u00e4t Heidelberg  Heidelberg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,5]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc04109b"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/c5cs00697j"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0637494"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200703518"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200503649"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200705024"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja8070072"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja307714m"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202009814"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b12444"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/om400281v"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja208675p"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201006918"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201605403"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja305248f"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature12435"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b03432"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b02335"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.7b00014"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202209655"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b09364"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201803356"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b02870"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c04937"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja2099744"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202313636"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b10204"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c10922"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202417581"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202519355"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b03287"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b05520"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202302332"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202012218"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202524828"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/d0sc02686g"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199601291"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic00313a039"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521\u20103749(199805)624:5<813::AID\u2010ZAAC813>3.0.CO;2\u20102"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19966220120"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199417541"},{"key":"e_1_2_8_43_1","volume-title":"Encyclopedia of Inorganic and Bioinorganic Chemistry","author":"Weetman C.","year":"2011"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521\u20103773(20001201)39:23<4274::AID\u2010ANIE4274>3.0.CO;2\u2010K"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c10222"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202007530"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010018\u20100037\u2010y"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557\u2010022\u201001000\u20104"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199105641"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010025\u201009941\u20109"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja9716463"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0022\u2010328X(00)00279\u20105"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja504448v"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/om300216g"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic50218a044"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1039\/c4dt02051k"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201200954"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202209502"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c01580"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201813619"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2024.07.017"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic301507c"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201300031"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2010.11.044"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja993537p"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201100615"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1039\/d0sc05526c"},{"key":"e_1_2_8_68_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053273321009086"},{"key":"e_1_2_8_69_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570\u2010018\u20100052\u20104"},{"key":"e_1_2_8_70_1","doi-asserted-by":"publisher","DOI":"10.1021\/om0209935"},{"key":"e_1_2_8_71_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC04637G"},{"key":"e_1_2_8_72_1","doi-asserted-by":"publisher","DOI":"10.1039\/d2cc05786g"},{"key":"e_1_2_8_73_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010026\u201069607\u20106"},{"key":"e_1_2_8_74_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic2005419"},{"key":"e_1_2_8_75_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b00034"},{"key":"e_1_2_8_76_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2003.10.008"},{"key":"e_1_2_8_77_1","unstructured":"Deposition numbers 2538244\u20132538246 2562647\u20132562652 and 2564596 contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe Access Structures service."},{"key":"e_1_2_8_78_1","doi-asserted-by":"publisher","DOI":"10.1039\/c9dt03111a"},{"key":"e_1_2_8_79_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889886089835"},{"key":"e_1_2_8_80_1","doi-asserted-by":"publisher","DOI":"10.1107\/S1600576714022985"},{"key":"e_1_2_8_81_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767307043930"},{"key":"e_1_2_8_82_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053273314026370"},{"key":"e_1_2_8_83_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053229614024218"},{"key":"e_1_2_8_84_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889811043202"},{"key":"e_1_2_8_85_1","doi-asserted-by":"publisher","DOI":"10.1107\/S1600576715005580"},{"key":"e_1_2_8_86_1","unstructured":"D.Kratzert can be found underhttps:\/\/www.xs3.uni\u2010freiburg.de\/research\/finalcif accessed July 2026."},{"key":"e_1_2_8_87_1","doi-asserted-by":"publisher","DOI":"10.1021\/om3000423"},{"key":"e_1_2_8_88_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0004608"},{"key":"e_1_2_8_89_1","doi-asserted-by":"publisher","DOI":"10.1002\/wcms.81"},{"key":"e_1_2_8_90_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0040021"},{"key":"e_1_2_8_91_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.5090222"},{"key":"e_1_2_8_92_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.4993215"},{"key":"e_1_2_8_93_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.3700154"},{"key":"e_1_2_8_94_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.464913"},{"key":"e_1_2_8_95_1","doi-asserted-by":"publisher","DOI":"10.1103\/physrevb.37.785"},{"key":"e_1_2_8_96_1","doi-asserted-by":"publisher","DOI":"10.1139\/p80\u2010159"},{"key":"e_1_2_8_97_1","doi-asserted-by":"publisher","DOI":"10.1039\/B515623H"},{"key":"e_1_2_8_98_1","doi-asserted-by":"publisher","DOI":"10.1039\/B508541A"},{"key":"e_1_2_8_99_1","doi-asserted-by":"publisher","DOI":"10.1021\/ct100199k"},{"key":"e_1_2_8_100_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp9716997"},{"key":"e_1_2_8_101_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.22885"},{"key":"e_1_2_8_102_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2004.06.011"},{"key":"e_1_2_8_103_1","doi-asserted-by":"publisher","DOI":"10.1021\/ct800503d"},{"key":"e_1_2_8_104_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.1056"},{"key":"e_1_2_8_105_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.34.7406"},{"key":"e_1_2_8_106_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.33.8822"},{"key":"e_1_2_8_107_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.3382344"},{"key":"e_1_2_8_108_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.21759"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.6333732","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.6333732","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.6333732","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T13:22:18Z","timestamp":1790601738000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.6333732"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,5]]},"references-count":107,"journal-issue":{"issue":"40","published-print":{"date-parts":[[2026,9,28]]}},"alternative-id":["10.1002\/anie.6333732"],"URL":"https:\/\/doi.org\/10.1002\/anie.6333732","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,5]]},"assertion":[{"value":"2026-05-08","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-22","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-05","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e6333732"}}