{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,4]],"date-time":"2026-10-04T10:53:13Z","timestamp":1791111193037,"version":"4.1.0"},"reference-count":52,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,4]],"date-time":"2026-10-04T00:00:00Z","timestamp":1791072000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,4]],"date-time":"2026-10-04T00:00:00Z","timestamp":1791072000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22461142141"],"award-info":[{"award-number":["22461142141"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004607","name":"Natural Science Foundation of Guangxi Province","doi-asserted-by":"publisher","award":["2026GXNSFBA00640369"],"award-info":[{"award-number":["2026GXNSFBA00640369"]}],"id":[{"id":"10.13039\/501100004607","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004607","name":"Natural Science Foundation of Guangxi Province","doi-asserted-by":"publisher","award":["2025GXNSFBA069409"],"award-info":[{"award-number":["2025GXNSFBA069409"]}],"id":[{"id":"10.13039\/501100004607","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Nickel (Ni) is an attractive non\u2010noble\u2010metal catalyst for the water\u2010gas shift reaction (WGSR), yet strong CO adsorption and competing methanation severely limit its activity and selectivity. Herein, we develop a series of NiCe layered double hydroxide\u2010derived catalysts (NCO\u2010\n                    <jats:italic>T<\/jats:italic>\n                    ) through reduction\u2010induced Ni exsolution. The optimized NCO\u2010450 catalyst achieves 92.53% CO conversion and an H\n                    <jats:sub>2<\/jats:sub>\n                    production rate of 103.24 \u00b5mol\u00b7g\n                    <jats:sub>cat<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7s\n                    <jats:sup>\u22121<\/jats:sup>\n                    at ambient pressure and a catalyst temperature of 83\u00b0C. In situ spectroscopic analyses and theoretical calculations reveal that isolated interfacial oxygen vacancies (O\n                    <jats:sub>V<\/jats:sub>\n                    s) stabilize the active Ni\n                    <jats:sup>\u03b4+<\/jats:sup>\n                    \u2500O\n                    <jats:sub>V<\/jats:sub>\n                    \u2500Ce\n                    <jats:sup>3+<\/jats:sup>\n                    motif responsible for the superior WGSR performance. Photoexcitation\u2010induced directional interfacial charge transfer from Ni to CeO\n                    <jats:sub>2\u2010<\/jats:sub>\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    enhances the electronic metal\u2013support interaction and continuously regenerates this active interfacial state, thereby moderating CO adsorption, promoting H\n                    <jats:sub>2<\/jats:sub>\n                    O activation, and suppressing competing methanation. This work offers a rational design strategy for developing low\u2010cost transition\u2010metal catalysts with superior low\u2010temperature activity and high selectivity.\n                  <\/jats:p>","DOI":"10.1002\/anie.6374020","type":"journal-article","created":{"date-parts":[[2026,10,4]],"date-time":"2026-10-04T10:20:47Z","timestamp":1791109247000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Photo\u2010Enhanced Electronic Metal\u2013Support Interaction Boosts Low\u2010Temperature Water\u2013Gas Shift Reaction via Ni\n                    <sup>\u03b4+<\/sup>\n                    \u2013O\n                    <sub>V<\/sub>\n                    \u2013Ce\n                    <sup>3+<\/sup>\n                    Interfacial Redox Cycling"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0009-3887-1921","authenticated-orcid":false,"given":"Jie","family":"Tian","sequence":"first","affiliation":[{"name":"School of Resources Environment and Materials Guangxi Key Laboratory of Processing for Non\u2010ferrous Metals and Featured Materials and International Joint Center of Nature\u2010Inspired Carbon Neutrality Solutions Guangxi University Nanning Guangxi P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziyang","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Resources Environment and Materials Guangxi Key Laboratory of Processing for Non\u2010ferrous Metals and Featured Materials and International Joint Center of Nature\u2010Inspired Carbon Neutrality Solutions Guangxi University Nanning Guangxi P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-1319-4919","authenticated-orcid":false,"given":"Anxiang","family":"Guan","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering State Key Laboratory of Featured Metal Materials and Life\u2010cycle Safety For Composite Structures Guangxi University  Nanning Guangxi P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yaqin","family":"Hou","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Coal Conversion Institute of Coal Chemistry Chinese Academy of Sciences  Taiyuan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haiyang","family":"Yu","sequence":"additional","affiliation":[{"name":"Materials Genome Institute Shanghai University  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0007-3433-1480","authenticated-orcid":false,"given":"Xianyuan","family":"Sun","sequence":"additional","affiliation":[{"name":"School of Resources Environment and Materials Guangxi Key Laboratory of Processing for Non\u2010ferrous Metals and Featured Materials and International Joint Center of Nature\u2010Inspired Carbon Neutrality Solutions Guangxi University Nanning Guangxi P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yaqi","family":"Zhu","sequence":"additional","affiliation":[{"name":"School of Resources Environment and Materials Guangxi Key Laboratory of Processing for Non\u2010ferrous Metals and Featured Materials and International Joint Center of Nature\u2010Inspired Carbon Neutrality Solutions Guangxi University Nanning Guangxi P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinyu","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Low\u2010Carbon Energy and Power Engineering China University of Mining and Technology  Xuzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haojie","family":"Tian","sequence":"additional","affiliation":[{"name":"School of Resources Environment and Materials Guangxi Key Laboratory of Processing for Non\u2010ferrous Metals and Featured Materials and International Joint Center of Nature\u2010Inspired Carbon Neutrality Solutions Guangxi University Nanning Guangxi P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jie","family":"Lu","sequence":"additional","affiliation":[{"name":"School of Resources Environment and Materials Guangxi Key Laboratory of Processing for Non\u2010ferrous Metals and Featured Materials and International Joint Center of Nature\u2010Inspired Carbon Neutrality Solutions Guangxi University Nanning Guangxi P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4812-4331","authenticated-orcid":false,"given":"Jia Hong","family":"Pan","sequence":"additional","affiliation":[{"name":"School of Resources Environment and Materials Guangxi Key Laboratory of Processing for Non\u2010ferrous Metals and Featured Materials and International Joint Center of Nature\u2010Inspired Carbon Neutrality Solutions Guangxi University Nanning Guangxi P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,4]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010018\u201007937\u2010w"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1192449"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010020\u201003130\u20106"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aah4321"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adr9120"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2015.04.031"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b08984"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c02489"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms8915"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201308145"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c00388"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c03664"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c09102"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b03117"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c12061"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mcat.2024.114777"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201410697"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c01561"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202219299"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2021.120551"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202513933"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c08847"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c09353"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2026.167113"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3ee40656c"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201902324"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010019\u201011407\u20102"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2016.09.021"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja312646d"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c04366"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4500"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1QM00132A"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b01606"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010023\u201001418\u20101"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c00327"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c02669"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010026\u201072447\u2010z"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010025\u201008684\u2010x"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.6c01982"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202415642"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202505668"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202316384"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2003.09.006"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2022.123186"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5TA02030A"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201045031\u20106"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201056161\u2010w"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0768237"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202415774"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202516103"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6c02042"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.4c00518"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.6374020","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.6374020","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.6374020","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,4]],"date-time":"2026-10-04T10:20:48Z","timestamp":1791109248000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.6374020"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,10,4]]},"references-count":52,"alternative-id":["10.1002\/anie.6374020"],"URL":"https:\/\/doi.org\/10.1002\/anie.6374020","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,10,4]]},"assertion":[{"value":"2026-08-03","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-28","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-10-04","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e6374020"}}