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Here, we propose a novel paradigm converting PFAS\u2010containing wastewater into efficient catalysts, unlocking the catalytic potential of these \u201cforever chemicals\u201d. As the first example of this paradigm, PFAS\u2010containing wastewater was transformed into F\u2010containing biomass (here shrimp shells)\u2010derived catalysts, achieving PFAS removal efficiency exceeding 99.9%. The catalyst exhibited outstanding performance in PET recycling at a low catalyst loading (2.5 wt%), efficiently promoting methanolysis and hydrolysis to yield the corresponding monomers in near\u2010quantitative yields, surpassing commercial carbon and biochar catalysts. This performance arises from the combined presence of electron\u2011deficient carbon sites generated by fluorine species and nitrogen vacancies, both of which contribute to the activation of ester bonds. The catalyst also showed broad applicability and stability across 23 real\u2010world plastic wastes, including mixed PET and additive\u2010containing plastics. Moreover, PFAS incorporation into metal oxides, supported metals, and porous carbons was demonstrated, laying the groundwork for diverse PFAS\u2010derived catalytic applications. This work reconceptualizes PFAS as a resource, opening new avenues for sustainable valorization and functional catalyst development.<\/jats:p>","DOI":"10.1002\/anie.6397678","type":"journal-article","created":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T11:20:35Z","timestamp":1790076035000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Unlocking the Catalytic Potential of PFAS: Upcycling Forever Chemicals Into Effective Catalysts"],"prefix":"10.1002","author":[{"given":"Mengying","family":"Zheng","sequence":"first","affiliation":[{"name":"State Key Laboratory of Water Pollution Control and Green Resource Recycling School of the Environment Nanjing University  Nanjing China"},{"name":"Institute For the Environment and Health Nanjing University Suzhou Campus  Suzhou 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