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Herein, hollow CoFe@NC nanocages were synthesized through a cyanometalate\u2010assisted transformation of ZIF\u201067 nanocubes followed by reductive calcination, producing metallic CoFe alloy domains confined within an N\u2010doped graphitic carbon framework. The optimized CoFe@NC\u2010600 catalyst exhibited a hollow architecture, abundant accessible active sites, and strong metal\u2013carbon interfacial coupling for efficient peroxymonosulfate (PMS) activation. Under visible\u2010light irradiation, the CoFe@NC\u2010600\/PMS system achieved 99.2% degradation efficiency toward real PET textile substrates, confirmed by gravimetric analysis, total organic carbon (TOC) measurement, and degradation product identification. Beyond conventional semiconductor photocatalysis, this work demonstrates that metallic alloy\u2013carbon interfaces can efficiently utilize visible light through coupled photothermal conversion, interfacial electronic activation and CoFe redox mediation to drive PMS oxidation. X\u2010ray photoelectron spectroscopy (XPS), electrochemical impedance spectroscopy (EIS), radical quenching experiments and density functional theory (DFT) calculations reveal that the CoFe\/N\u2010doped carbon interface facilitates PMS adsorption, electron transfer and O\u2500O bond activation, promoting the generation of radical and nonradical reactive species. This study provides new insights into metal\u2013carbon hybrid catalysts for advanced oxidation processes and offers a sustainable approach for the remediation of persistent polymer wastes.<\/jats:p>","DOI":"10.1002\/anie.6433467","type":"journal-article","created":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T12:55:00Z","timestamp":1786452900000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["MOF\u2010Derived Hollow CoFe@NC Nanocages for Highly Efficient Degradation of Textile Fibers"],"prefix":"10.1002","volume":"65","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4603-1841","authenticated-orcid":false,"given":"Shafqat","family":"Ali","sequence":"first","affiliation":[{"name":"State Key Laboratory of New Textile Materials and Advanced Processing Technologies National Local Joint Laboratory for Advanced Textile Processing and Clean Production Wuhan Textile University  Wuhan 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