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Herein, we propose a chain rigidity engineering strategy to promote the formation of closed pores and inter\u2010graphitic domain channels in resin\u2010derived HC, enabling synergistic optimization plateau capacity and rate capability. The chain rigidity of 3\u2010aminophenol\u2010formaldehyde resin was enhanced by utilizing the weak coordination between Zn\n                    <jats:sup>2+<\/jats:sup>\n                    and the amino group of 3\u2010aminophenol to suppress the amino\u2010site\u2010mediated flexible bridging pathway during polymerization. Improved chain rigidity introduces rich inter\u2010chain voids in the resin, promoting the formation of closed pores in HC; meanwhile, it effectively suppresses carbon layer rearrangement to construct abundant ion diffusion channels between short and thin graphitic domains together with enlarged interlayer spacing, thereby significantly enhancing bulk diffusion kinetics. As a result, the optimized HC delivers an ultrahigh reversible capacity of 437.9 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    with a plateau capacity of 309.9 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    and excellent rate performance (293.4 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 2 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). This work provides insights into the role of polymer chain rigidity in promoting the formation of closed pores and ion diffusion channels in HC.\n                  <\/jats:p>","DOI":"10.1002\/anie.6458234","type":"journal-article","created":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T17:03:35Z","timestamp":1786554215000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Chain Rigidity Modulating Closed Pore and Inter\u2010Graphitic Domain Channels in Resin\u2010Derived Hard Carbon for Fast Plateau Sodium Storage"],"prefix":"10.1002","volume":"65","author":[{"given":"Chuang","family":"Qiu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering, Beijing Key Laboratory of Electrochemical Process and Technology for Materials Beijing University of Chemical Technology  Beijing 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