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Herein, we reveal the H\u2010spillover mediated regulatory role of oxide supports, which changed the CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation selectivity on In\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    \u2010based catalysts. By replacing the supports from TiO\n                    <jats:sub>2<\/jats:sub>\n                    to ZrO\n                    <jats:sub>2<\/jats:sub>\n                    , the primary product of CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation experiences a significant shift from carbon monoxide (95.6%) to methanol (84.2%). In situ characterization and theoretical modeling evidence that the degree of H\u2010spillover influences the distribution of surface hydrogen species on In\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    \u2010based catalysts, affecting the hydrogenation behavior of formate intermediates and the product distribution. The results illustrate the intrinsic relationship between surface hydrogen atom concentration and methanol synthesis rate in catalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation over In\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    \u2010based catalysts. This provides the potential to design selective catalysts for CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation by modulating the degree of H\u2010spillover.\n                  <\/jats:p>","DOI":"10.1002\/anie.6478038","type":"journal-article","created":{"date-parts":[[2026,2,17]],"date-time":"2026-02-17T08:23:38Z","timestamp":1771316618000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Hydrogen Aggregation Enhances CO\n                    <sub>2<\/sub>\n                    Hydrogenation to Methanol Over In\n                    <sub>2<\/sub>\n                    O\n                    <sub>3<\/sub>\n                    \u2010Based Catalysts"],"prefix":"10.1002","volume":"65","author":[{"given":"Chunliang","family":"Wang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization School of Metallurgical and Energy 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