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Reactions of XeO\n                    <jats:sub>3<\/jats:sub>\n                    in aqueous or CH\n                    <jats:sub>3<\/jats:sub>\n                    CN solutions with the polytopic nitrogen bases, 2,2\u2032\u2010bipyridine (2,2\u2032\u2010bipy), 1,10\u2010phenanthroline (1,10\u2010phen), 4,4\u2032\u2010bipyridine (4,4\u2032\u2010bipy), hexamethylenetetramine (HMTA), and 1,4\u2010diazabicyclo[2.2.2]octane (DABCO) yield 1\u2010, 2\u2010, and 3\u2010D supramolecular XeO\n                    <jats:sub>3<\/jats:sub>\n                    complexes. The low\u2010temperature X\u2010ray crystal structures of room\u2010temperature\u2010stable O\n                    <jats:sub>3<\/jats:sub>\n                    Xe(2,2\u2032\u2010bipy), O\n                    <jats:sub>3<\/jats:sub>\n                    Xe(1,10\u2010phen), and O\n                    <jats:sub>3<\/jats:sub>\n                    Xe(4,4\u2032\u2010bipy), consist of Xe\u2010\u2010\u2010O \u03c3\u2010hole\u2010bonded \u2010(\u2010O\u2550Xe(O\n                    <jats:sub>2<\/jats:sub>\n                    )\u2010\u2010)\u2010\n                    <jats:sub>\u221e<\/jats:sub>\n                    chains that coordinate through Xe\u2010\u2010\u2010N \u03c3\u2013hole bonds. Shock\u2010insensitive O\n                    <jats:sub>3<\/jats:sub>\n                    Xe(HMTA)(H\n                    <jats:sub>2<\/jats:sub>\n                    O) is crosslinked by \u2010(\u2010Xe(O\n                    <jats:sub>2<\/jats:sub>\n                    )O\u2010\u2010\u2010HO(H)\u2010\u2010)\u2010\n                    <jats:sub>\u221e<\/jats:sub>\n                    chains that are Xe\u2010\u2010\u2010N and Xe\u2010\u2010\u2010O coordinated to HMTA and H\n                    <jats:sub>2<\/jats:sub>\n                    O to give 3\u2010D networks, whereas highly shock\u2010sensitive and explosive (O\n                    <jats:sub>3<\/jats:sub>\n                    Xe)\n                    <jats:sub>2<\/jats:sub>\n                    (HMTA) forms 3\u2010D networks in which \u2010(\u2010O\u2550Xe(O\n                    <jats:sub>2<\/jats:sub>\n                    )\u2010\u2010)\u2010\n                    <jats:sub>\u221e<\/jats:sub>\n                    chains couple to form layers that are Xe\u2010\u2010\u2010N coordinated to HMTA. Reaction of DABCO with XeO\n                    <jats:sub>3<\/jats:sub>\n                    in HF(aq) yields stable [HDABCO]\n                    <jats:sub>2<\/jats:sub>\n                    [(\n                    <jats:italic>\u03bc<\/jats:italic>\n                    \u2010FXeO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ]\u00b7H\n                    <jats:sub>2<\/jats:sub>\n                    O and [H\n                    <jats:sub>2<\/jats:sub>\n                    DABCO][F][H\n                    <jats:sub>2<\/jats:sub>\n                    F\n                    <jats:sub>3<\/jats:sub>\n                    ] salts. The XeO\n                    <jats:sub>3<\/jats:sub>\n                    moieties of [(\n                    <jats:italic>\u03bc<\/jats:italic>\n                    \u2010FXeO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ]\n                    <jats:sup>2\u2212<\/jats:sup>\n                    form crosslinked \u2010(\u2010HOH\u2010\u2010[\u2010O\u2550Xe(O)\n                    <jats:sub>2<\/jats:sub>\n                    (\n                    <jats:italic>\u03bc<\/jats:italic>\n                    \u2010F)\n                    <jats:sub>2<\/jats:sub>\n                    (O\n                    <jats:sub>2<\/jats:sub>\n                    )Xe\u2550O\u2010]\u2010\u2010)\u2010\n                    <jats:sub>\u221e<\/jats:sub>\n                    chains that are Xe\u2010\u2010\u2010N coordinated to [HDABCO]\n                    <jats:sup>+<\/jats:sup>\n                    . The XeO\n                    <jats:sub>3<\/jats:sub>\n                    complexes provide examples of Xe(VI)\u2010\u2010\u2010N \u03c3\u2013hole bonds with sp\n                    <jats:sup>2<\/jats:sup>\n                    \u2010 and sp\n                    <jats:sup>3<\/jats:sup>\n                    \u2010hybridized polytopic N\u2010bases, where O\n                    <jats:sub>3<\/jats:sub>\n                    Xe(2,2\u2032\u2010bipy) and O\n                    <jats:sub>3<\/jats:sub>\n                    Xe(1,10\u2010phen) are unique examples of chelated noble\u2010gas centers, and O\n                    <jats:sub>3<\/jats:sub>\n                    Xe(HMTA)(H\n                    <jats:sub>2<\/jats:sub>\n                    O) is a rare example of a Xe\u2010\u2010\u2010O \u03c3\u2013hole bonded noble\u2010gas hydrate.\n                  <\/jats:p>","DOI":"10.1002\/anie.6506301","type":"journal-article","created":{"date-parts":[[2026,9,17]],"date-time":"2026-09-17T06:19:04Z","timestamp":1789625944000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Syntheses, X\u2010ray Crystal Structures, and Raman Spectra of Self\u2010Assembled XeO\n                    <sub>3<\/sub>\n                    Chain and Network Complexes of Polytopic sp\n                    <sup>2<\/sup>\n                    \u2010 and sp\n                    <sup>3<\/sup>\n                    \u2010Nitrogen Bases"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8120-3771","authenticated-orcid":false,"given":"James T.","family":"Goettel","sequence":"first","affiliation":[{"name":"Department of Chemistry McMaster University  Hamilton Ontario Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8716-2330","authenticated-orcid":false,"given":"H\u00e9l\u00e8ne P. 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