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However, achieving C\u2500C coupling under mild conditions is a significant challenge, primary due to the high energy barriers associated with C\u2500O bond cleavage via conventional carbide or CO insertion mechanisms. In this study, we propose an alternative strategy for C\u2500C coupling by chirality\u2010induced spin polarization in chiral nanostructured Co nanoparticles (CNCN) under mild temperature conditions. The *OCCO intermediate is hydrogenated to form C\n                    <jats:sub>2+<\/jats:sub>\n                    alcohols at lower temperatures. Subsequently, these alcohols are converted into hydrocarbons through the Br\u00f6nsted acid sites of H\u2010type mesoporous\n                    <jats:bold>MFI<\/jats:bold>\n                    zeolite (HMMZ) support. The CNCN\u2010confined HMMZ catalyst exhibits significantly enhanced Co metal time yield of 96.3 mol\n                    <jats:sub>CO<\/jats:sub>\n                    kg\n                    <jats:sub>Co<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    and C\n                    <jats:sub>5+<\/jats:sub>\n                    hydrocarbons selectivity of 85.6% at 443 K. This work demonstrates an effective strategy for the activation C\n                    <jats:sub>1<\/jats:sub>\n                    compounds and promotion of critical intermediate, paving the way for the production of multicarbon products.\n                  <\/jats:p>","DOI":"10.1002\/anie.6583201","type":"journal-article","created":{"date-parts":[[2026,8,29]],"date-time":"2026-08-29T16:10:01Z","timestamp":1788019801000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Chiral Nanostructured Cobalt Nanoparticles Confined in Zeolite for Syngas Conversion to Liquid Fuels at Low Temperature"],"prefix":"10.1002","volume":"65","author":[{"given":"Neng","family":"Gong","sequence":"first","affiliation":[{"name":"School of Chemical Science and Engineering Tongji University  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guodong","family":"Xie","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of High\u2010resolution Electron Microscopy &amp; School of Physical Science and Technology Shanghai Tech University  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4814-3740","authenticated-orcid":false,"given":"Yanhang","family":"Ma","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of High\u2010resolution Electron Microscopy &amp; School of Physical Science and Technology Shanghai Tech University  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wanning","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Synergistic Chem\u2010Bio Synthesis School of Chemistry and Chemical Engineering Frontiers Science Center for Transformative Molecules Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs Shanghai Jiao Tong University  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-5019-1413","authenticated-orcid":false,"given":"Yuxi","family":"Fang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Synergistic Chem\u2010Bio Synthesis School of Chemistry and Chemical Engineering Frontiers Science Center for Transformative Molecules Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs Shanghai Jiao Tong University  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,29]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr050972v"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00502H"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00905A"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c03404"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.checat.2021.05.011"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/cs500784v"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201411708"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-018-0144-z"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-05755-8"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2021.12.016"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-021-01183-0"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202306786"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CY01422E"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-860X(03)00489-7"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2018.02.009"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b00834"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC05528B"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2013.03.004"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c01016"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2022.126115"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-17044-4"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c02780"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c04162"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c09168"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2007.03.002"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2007.09.018"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2007.11.028"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/cite.330421808"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.0c06107"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2024.102390"},{"key":"e_1_2_8_32_1","first-page":"28214","article-title":"Chiral Nanostructured Ag Films for Multicarbon Products From CO2 Electroreduction","volume":"146","author":"Zhang W. 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