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Their highly ordered, quasi\u2010molecular structure effectively promotes electron transfer and optimizes charge deposition kinetics, thereby significantly enhancing the catalytic activity and stability of electrochemical oxygen reduction reactions. Here, we constructed a single\u2010atom\u2010nanoparticle dual\u2010engine catalyst (Fe\n                    <jats:sub>3<\/jats:sub>\n                    C\/Fe\u2010NC\n                    <jats:sub>1050<\/jats:sub>\n                    ) by in situ domain\u2010confined complexation of ZIF\u20108(Zn) using {Fe\n                    <jats:sub>3<\/jats:sub>\n                    O} as a core metal\u2010oxo cluster. The unique flexible ligand\u2010carboxylate group of {Fe\n                    <jats:sub>3<\/jats:sub>\n                    O} clusters provide a protective barrier for the metal atoms distribution during pyrolysis, work in synergy with the ZIF\u20108 framework to provide a conductive substrate. The precisely exposed Fe\n                    <jats:sub>3<\/jats:sub>\n                    C (110) crystal plane modulates the electronic structure of neighboring Fe\u2010N\n                    <jats:sub>4<\/jats:sub>\n                    active sites, thus reducing the adsorption energy of key step O\n                    <jats:sub>2<\/jats:sub>\n                    \u2192*OOH and endowing the material with excellent methanol resistance and stability. Structural characterization and theoretical calculations reveal that the synergistic interaction between {Fe\n                    <jats:sub>3<\/jats:sub>\n                    O} clusters and the carbon substrate provides a stable conductive network and active sites, achieving a maximum power density of 249.0\u00a0mW cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    in alkaline zinc\u2010air batteries and demonstrates exceptionally long cycle life of 700\u00a0h at the current density of 2.0\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . This design provides crucial insights for the nanoengineering of metal\u2010oxo clusters and atomic\u2010scale design of catalysts.\n                  <\/jats:p>","DOI":"10.1002\/anie.6643887","type":"journal-article","created":{"date-parts":[[2026,6,11]],"date-time":"2026-06-11T06:02:57Z","timestamp":1781157777000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Unlocking Durable High\u2010Power Zn\u2010Air Batteries: {Fe\n                    <sub>3<\/sub>\n                    O} Molecular Furnace\u2010Forged Dual\u2010Site Catalysts Enabling Synergistic Oxygen Reduction in Alkaline Media"],"prefix":"10.1002","volume":"65","author":[{"given":"Jia\u2010Qi","family":"Lv","sequence":"first","affiliation":[{"name":"Jilin Provincial Science and Technology Innovation Center of Optical Materials and Chemistry School of Chemistry and Environmental Engineering Changchun University of Science and Technology  Changchun China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qianqian","family":"Liu","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education Northeast Normal University  Changchun China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhi\u2010Da","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Supramolecular Structure and Materials Institute of Theoretical Chemistry College of Chemistry Jilin University  Changchun China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3342-1966","authenticated-orcid":false,"given":"Zhong\u2010Min","family":"Su","sequence":"additional","affiliation":[{"name":"Jilin Provincial Science and Technology Innovation Center of Optical Materials and Chemistry School of Chemistry and Environmental Engineering Changchun University of Science and Technology  Changchun China"},{"name":"State Key Laboratory of Supramolecular Structure and Materials Institute of Theoretical Chemistry College of Chemistry Jilin University  Changchun China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8148-0303","authenticated-orcid":false,"given":"Hong\u2010Ying","family":"Zang","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education Northeast Normal University  Changchun China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,6,10]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202503019"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201063540\u2010w"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature11115"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201045990\u2010w"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5c11814"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202514862"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010021\u201000826\u20105"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010024\u201001144\u20101"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202424135"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202505937"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9EE03027A"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.170055"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202512498"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202202544"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00015C"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202202650"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12598\u2010024\u201002676\u2010y"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c06974"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202416711"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5c02353"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2025.102424"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202415265"},{"key":"e_1_2_8_24_1","unstructured":"Deposition numbers 2205952 (for 1) 2205956 (for 2) and 2205955 (for 3) contain the supplementary crystallographic data for this paper. 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