{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,17]],"date-time":"2026-10-17T18:40:27Z","timestamp":1792262427002,"version":"4.4.0"},"reference-count":50,"publisher":"Wiley","issue":"43","license":[{"start":{"date-parts":[[2026,8,30]],"date-time":"2026-08-30T00:00:00Z","timestamp":1788048000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,30]],"date-time":"2026-08-30T00:00:00Z","timestamp":1788048000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["92572203"],"award-info":[{"award-number":["92572203"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["92263206"],"award-info":[{"award-number":["92263206"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U23A20577"],"award-info":[{"award-number":["U23A20577"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52372168"],"award-info":[{"award-number":["52372168"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U24A20549"],"award-info":[{"award-number":["U24A20549"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52302209"],"award-info":[{"award-number":["52302209"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2022YFB2404400"],"award-info":[{"award-number":["2022YFB2404400"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004826","name":"Natural Science Foundation of Beijing Municipality","doi-asserted-by":"publisher","award":["L233004"],"award-info":[{"award-number":["L233004"]}],"id":[{"id":"10.13039\/501100004826","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,10,19]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Lithium\u2010rich layered oxides (LLOs) deliver high energy density via coupled cationic\/anionic redox, but high\u2010voltage oxygen activation generates radical\u2010rich interfaces that accelerate electrolyte decomposition, surface reconstruction, and mechanical failure. Although polyimide serves as an oxidation\u2010resistant interphase on LLO cathodes, its durability is limited by labile termini vulnerable to reactive oxygen species, whereas backbone fluorination compromises ionic transport. In this study, a terminally fluorinated polyimide (FPI) interphase is constructed on LLOs (LLO\u2010FPI) by introducing electron\u2010withdrawing \u2500CF\n                    <jats:sub>3<\/jats:sub>\n                    termini to elevate the interfacial electronic barrier, thereby mitigating oxidative attack and oxygen release while preserving backbone integrity. Terminal fluorination suppresses radical\u2010mediated degradation and parasitic oxidation, while the high\u2010modulus FPI interphase constrains stress\u2010driven particle cracking without sacrificing Li\n                    <jats:sup>+<\/jats:sup>\n                    kinetics. Consequently, LLO\u2010FPI exhibits exceptional long\u2010term cycling stability, retaining 80.8% capacity after 1000 cycles. A Si\/C||LLO\u2010FPI pouch cell delivers 409\u00a0Wh kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    with 90.1% capacity retention over 100 cycles. These findings identify terminal fluorination as a versatile strategy for durable high\u2010energy\u2010density batteries.\n                  <\/jats:p>","DOI":"10.1002\/anie.6759160","type":"journal-article","created":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T05:02:32Z","timestamp":1788152552000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Terminally Fluorinated Polyimide Interphase for Durable Lithium\u2010Rich Layered Oxide Cathodes"],"prefix":"10.1002","volume":"65","author":[{"given":"Chenghan","family":"Li","sequence":"first","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of New Energy Beijing University of Technology  Beijing China"},{"name":"Institute of Gongda\u2010Guochuang Advanced Battery Materials and Devices  Beijing China"},{"name":"College of Materials Science and Engineering State Key Laboratory of Materials Low\u2010Carbon Recycling Beijing University of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Juan","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of New Energy Beijing University of Technology  Beijing China"},{"name":"Institute of Gongda\u2010Guochuang Advanced Battery Materials and Devices  Beijing China"},{"name":"College of Materials Science and Engineering State Key Laboratory of Materials Low\u2010Carbon Recycling Beijing University of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pei","family":"Zou","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of New Energy Beijing University of Technology  Beijing China"},{"name":"Institute of Gongda\u2010Guochuang Advanced Battery Materials and Devices  Beijing China"},{"name":"College of Materials Science and Engineering State Key Laboratory of Materials Low\u2010Carbon Recycling Beijing University of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haozhe","family":"Du","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of New Energy Beijing University of Technology  Beijing China"},{"name":"Institute of Gongda\u2010Guochuang Advanced Battery Materials and Devices  Beijing China"},{"name":"College of Materials Science and Engineering State Key Laboratory of Materials Low\u2010Carbon Recycling Beijing University of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shu","family":"Zhao","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of New Energy Beijing University of Technology  Beijing China"},{"name":"Institute of Gongda\u2010Guochuang Advanced Battery Materials and Devices  Beijing China"},{"name":"College of Materials Science and Engineering State Key Laboratory of Materials Low\u2010Carbon Recycling Beijing University of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shiqi","family":"Liu","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of New Energy Beijing University of Technology  Beijing China"},{"name":"Institute of Gongda\u2010Guochuang Advanced Battery Materials and Devices  Beijing China"},{"name":"College of Materials Science and Engineering State Key Laboratory of Materials Low\u2010Carbon Recycling Beijing University of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenlei","family":"Chen","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of New Energy Beijing University of Technology  Beijing China"},{"name":"Institute of Gongda\u2010Guochuang Advanced Battery Materials and Devices  Beijing China"},{"name":"College of Materials Science and Engineering State Key Laboratory of Materials Low\u2010Carbon Recycling Beijing University of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shaojuan","family":"Huang","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of New Energy Beijing University of Technology  Beijing China"},{"name":"Institute of Gongda\u2010Guochuang Advanced Battery Materials and Devices  Beijing China"},{"name":"College of Materials Science and Engineering State Key Laboratory of Materials Low\u2010Carbon Recycling Beijing University of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuming","family":"Li","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of New Energy Beijing University of Technology  Beijing China"},{"name":"Institute of Gongda\u2010Guochuang Advanced Battery Materials and Devices  Beijing China"},{"name":"College of Materials Science and Engineering State Key Laboratory of Materials Low\u2010Carbon Recycling Beijing University of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuqiang","family":"Li","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of New Energy Beijing University of Technology  Beijing China"},{"name":"Institute of Gongda\u2010Guochuang Advanced Battery Materials and Devices  Beijing China"},{"name":"College of Materials Science and Engineering State Key Laboratory of Materials Low\u2010Carbon Recycling Beijing University of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guoqing","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of New Energy Beijing University of Technology  Beijing China"},{"name":"Institute of Gongda\u2010Guochuang Advanced Battery Materials and Devices  Beijing China"},{"name":"College of Materials Science and Engineering State Key Laboratory of Materials Low\u2010Carbon Recycling Beijing University of Technology  Beijing China"},{"name":"Beijing Create Energy &amp; Benefit Future Co., Ltd.  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenhui","family":"Bai","sequence":"additional","affiliation":[{"name":"Beijing Create Energy &amp; Benefit Future Co., Ltd.  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of New Energy Beijing University of Technology  Beijing China"},{"name":"Institute of Gongda\u2010Guochuang Advanced Battery Materials and Devices  Beijing China"},{"name":"College of Materials Science and Engineering State Key Laboratory of Materials Low\u2010Carbon Recycling Beijing University of Technology  Beijing China"},{"name":"Phylion Battery Co., Ltd.  Suzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xianwei","family":"Guo","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of New Energy Beijing University of Technology  Beijing China"},{"name":"Institute of Gongda\u2010Guochuang Advanced Battery Materials and Devices  Beijing China"},{"name":"College of Materials Science and Engineering State Key Laboratory of Materials Low\u2010Carbon Recycling Beijing University of Technology  Beijing China"},{"name":"Beijing Create Energy &amp; Benefit Future Co., Ltd.  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhengwei","family":"Wang","sequence":"additional","affiliation":[{"name":"Phylion Battery Co., Ltd.  Suzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao","family":"Feng","sequence":"additional","affiliation":[{"name":"Phylion Battery Co., Ltd.  Suzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0204-9943","authenticated-orcid":false,"given":"Haijun","family":"Yu","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of New Energy Beijing University of Technology  Beijing China"},{"name":"Institute of Gongda\u2010Guochuang Advanced Battery Materials and Devices  Beijing China"},{"name":"College of Materials Science and Engineering State Key Laboratory of Materials Low\u2010Carbon Recycling Beijing University of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,30]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570\u2010026\u201000821\u2010y"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201800561"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja3091438"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat3699"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwaf202"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010025\u201001777\u2010x"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570\u2010026\u201000801\u20102"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00875E"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2524"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jz400032v"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c08115"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adx5020"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202001358"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00139"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2018.03.037"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2022.09.032"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c00402"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c06363"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202515515"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201036384\u20105"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.abm1899"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201043792\u20100"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201025686\u20101"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201025611\u20106"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010020\u201017126\u20103"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202417796"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwae254"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201064396\u2010w"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010025\u201009565\u2010z"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010019\u201011015\u20100"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwaf217"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010023\u201001403\u20108"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010019\u20100387\u20101"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010025\u201001857\u2010y"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0EE00342E"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202521087"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwae436"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c11695"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.26599\/EMD.2025.9370077"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202402904"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201035934\u20101"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CS00873D"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp013735e"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201054998\u20101"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.3c02697"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202001413"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2021.01.006"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwab146"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.add5189"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201065250\u20109"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.6759160","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.6759160","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.6759160","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,17]],"date-time":"2026-10-17T17:41:04Z","timestamp":1792258864000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.6759160"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,30]]},"references-count":50,"journal-issue":{"issue":"43","published-print":{"date-parts":[[2026,10,19]]}},"alternative-id":["10.1002\/anie.6759160"],"URL":"https:\/\/doi.org\/10.1002\/anie.6759160","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,30]]},"assertion":[{"value":"2026-06-29","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-22","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-30","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e6759160"}}