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However, due to the lack of quantitative descriptor, such effect has been understood largely in a qualitative manner. To address this issue, a series of reticular metal\u2010organic frameworks (MOFs) with diverse functional groups (MIP\u2010206\u2010X, X = OH, OCH\n                    <jats:sub>3<\/jats:sub>\n                    , H, Cl, and F) were synthesized, and Pt NPs with similar sizes and loadings were incorporated to afford Pt@MIP\u2010206\u2010X for ammonia borane methanolysis. X\u2010ray absorption near edge structure (XANES) was adopted to determine the d\u2010orbital occupancy of Pt, and the electronic contribution from MOFs was quantified as the descriptor\n                    <jats:italic>\u0394e<\/jats:italic>\n                    , which was demonstrated to accurately describe the Pt\u2010methanol adsorption strength (quantified by activation entropy and methanol desorption temperature) and exhibit an excellent linear correlation with catalytic activity. Isotopic analyses and DFT calculations revealed that a larger\n                    <jats:italic>\u0394e<\/jats:italic>\n                    strengthens methanol adsorption on Pt, promotes O\u2500H bond cleavage as the rate\u2010determining step (RDS), and leads to enhanced activity.\n                  <\/jats:p>","DOI":"10.1002\/anie.6798793","type":"journal-article","created":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T15:57:38Z","timestamp":1785427058000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Quantifying Microenvironment Effect on Metal Electronic Structure With Experimentally Accessible Descriptor: Examples of MOF\u2010Incorporated Pt Catalysts"],"prefix":"10.1002","volume":"65","author":[{"given":"Weidong","family":"Zhang","sequence":"first","affiliation":[{"name":"Hefei National Research Center for Physical Sciences At the Microscale, Department of Chemistry University of Science and Technology of China  Anhui P. 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