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To circumvent this thermodynamic barrier, we report a deep eutectic solvent (DES)\u2010mediated strategy that leverages a dynamically crosslinked hydrogen\u2010bonding network to kinetically suppress long\u2010range ordering. Utilizing a DES architecture composed of 3\u2010aminopiperidine dihydrochloride and 2\u2010hydroxypropionamide, we successfully fabricate amorphous indium chloride glasses that preserve essential short\u2010range structural motifs while entirely eliminating lattice crystallinity. This rigid yet adaptive matrix facilitates efficient intersystem crossing through enhanced spin\u2010orbit coupling and minimizes nonradiative dissipation, thereby enabling robust afterglow emission. Furthermore, the strategic incorporation of [SbCl\n                    <jats:sub>6<\/jats:sub>\n                    ]\n                    <jats:sup>3\u2212<\/jats:sup>\n                    centers and organic fluorophores allows for precise modulation of excited\u2010state dynamics via host\u2010guest energy transfer and triplet excitons harvesting, yielding broad\u2010spectrum luminescence from blue to red. These hybrid glasses integrate prompt fluorescence, self\u2010trapped exciton emission, and room\u2010temperature phosphorescence, achieving a maximum lifetime of 283.41 ms and a photoluminescence quantum yield of 46.90%. This multifunctional platform demonstrates significant potential for multilevel anti\u2010counterfeiting and spatiotemporal information encoding. Ultimately, this work establishes DES chemistry as a versatile paradigm for customizing HMH glasses, paving the way for programmable, high\u2010performance photofunctional materials.\n                  <\/jats:p>","DOI":"10.1002\/anie.6909891","type":"journal-article","created":{"date-parts":[[2026,7,21]],"date-time":"2026-07-21T11:56:59Z","timestamp":1784635019000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Deep Eutectic Solvent Matrix for Hybrid Indium Chloride Glasses With Tunable Luminescence"],"prefix":"10.1002","volume":"65","author":[{"given":"Ya","family":"Jiang","sequence":"first","affiliation":[{"name":"Department of Chemistry and Academy for Advanced Interdisciplinary Studies Southern University of Science and Technology (SUSTech)  Shenzhen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhishan","family":"Luo","sequence":"additional","affiliation":[{"name":"Department of 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