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Herein, we propose a node\u2010docking strategy to graft Co\u2010Salen molecular complexes onto Zr\u2010MOF (NKM\u2010906) to achieve the selective photoreduction of CO\n                    <jats:sub>2<\/jats:sub>\n                    to CO. Experimental results demonstrate that the NKM\u2010906 with unique SCU topology and microporous structure can effectively concentrate CO\n                    <jats:sub>2<\/jats:sub>\n                    molecules near the Co\u2010Salen active sites. Moreover, the confined Co\u2010Salen exhibits superior adsorption and activation toward CO\n                    <jats:sub>2<\/jats:sub>\n                    over H\n                    <jats:sub>2<\/jats:sub>\n                    O, which is a key factor in suppressing the HER. Density functional theory (DFT) calculations further indicate that, compared to other mononuclear (Ni, Cu, Zn, Mn) and binuclear (Co\n                    <jats:sub>2<\/jats:sub>\n                    ) metal\u2010Salen complexes, the mononuclear Co\u2010Salen complex exhibits superior performance in the adsorption and activation of CO\n                    <jats:sub>2<\/jats:sub>\n                    . As a result, the Co\u2010NKM\u2010906 demonstrates a notable CO generation rate of 2.63\u00a0mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    with a CO selectivity of 83% in a water\u2010containing system, indicating its outstanding catalytic efficacy in the selective photoreduction of CO\n                    <jats:sub>2<\/jats:sub>\n                    .\n                  <\/jats:p>","DOI":"10.1002\/anie.6945993","type":"journal-article","created":{"date-parts":[[2026,7,10]],"date-time":"2026-07-10T15:23:09Z","timestamp":1783696989000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Selective Photocatalytic CO\n                    <sub>2<\/sub>\n                    Reduction via Enhanced CO\n                    <sub>2<\/sub>\n                    Adsorption and Activation Over Co\u2010Salen Functionalized Zr\u2010MOF Catalyst"],"prefix":"10.1002","volume":"65","author":[{"given":"Mei","family":"Li","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering State Key Laboratory of Elemento\u2010Organic Chemistry Frontiers Science Center for New Organic Matter Academy for Advanced Interdisciplinary Studies Nankai University  Tianjin P. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hao","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering State Key Laboratory of Elemento\u2010Organic Chemistry Frontiers Science Center for New Organic Matter Academy for Advanced Interdisciplinary Studies Nankai University  Tianjin P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhen","family":"Fan","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering State Key Laboratory of Elemento\u2010Organic Chemistry Frontiers Science Center for New Organic Matter Academy for Advanced Interdisciplinary Studies Nankai University  Tianjin P. R. China"},{"name":"School of Physics and Opto\u2010Electronic Technology Baoji University of Arts and Sciences  Baoji P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanghe","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering State Key Laboratory of Elemento\u2010Organic Chemistry Frontiers Science Center for New Organic Matter Academy for Advanced Interdisciplinary Studies Nankai University  Tianjin P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7546-5580","authenticated-orcid":false,"given":"Jiandong","family":"Pang","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering State Key Laboratory of Elemento\u2010Organic Chemistry Frontiers Science Center for New Organic Matter Academy for Advanced Interdisciplinary Studies Nankai University  Tianjin P. R. 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