{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T04:20:59Z","timestamp":1791433259553,"version":"4.3.3"},"reference-count":40,"publisher":"Wiley","issue":"24","license":[{"start":{"date-parts":[[2026,4,27]],"date-time":"2026-04-27T00:00:00Z","timestamp":1777248000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,4,27]],"date-time":"2026-04-27T00:00:00Z","timestamp":1777248000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,6,8]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Achieving durable lithium\u2013sulfur batteries with minimal catalyst loading remains challenging, particularly for interlayer designs where catalytic efficiency is often compromised by nonuniform active\u2010site utilization. Here we demonstrate that diffusion\u2010regulated precursor growth enables the construction of atomically dispersed Co\u2013N\n                    <jats:sub>x<\/jats:sub>\n                    catalytic sites within a freestanding aramid nanofiber\u2010derived carbon interlayer. By synchronizing the bidirectional diffusion of metal ions and ligands, this process enforces spatially confined nucleation and homogeneous precursor evolution, yielding a uniformly accessible single\u2010atom catalytic architecture while preserving the intrinsic fibrous conduction network. The resulting interlayer simultaneously enhances polysulfide anchoring, accelerates bidirectional sulfur redox kinetics, and regulates Li\n                    <jats:sub>2<\/jats:sub>\n                    S nucleation and dissolution, as directly revealed by in situ Raman spectroscopy and electrochemical analyses. As a consequence, the system delivers exceptional cycling stability under high\u2010rate operation despite a low Co loading, highlighting the importance of diffusion\u2010regulated catalytic architectures for efficient sulfur redox regulation in lithium\u2013sulfur batteries.\n                  <\/jats:p>","DOI":"10.1002\/anie.7009531","type":"journal-article","created":{"date-parts":[[2026,4,28]],"date-time":"2026-04-28T05:05:32Z","timestamp":1777352732000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Contra\u2010Diffusion Engineering of Single\u2010Atom Catalytic Interlayers Enables Reversible Sulfur Redox Chemistry"],"prefix":"10.1002","volume":"65","author":[{"given":"Yan\u2010Jhang","family":"Chen","sequence":"first","affiliation":[{"name":"Department of Materials and Optoelectronic Science Center of Crystal Research National Sun Yat\u2010Sen University  Kaohsiung 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