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Here we report a photocatalytic platform in which Pt single atoms (Pt\n                    <jats:sub>SA<\/jats:sub>\n                    ) and Pt nanoparticles (Pt\n                    <jats:sub>NP<\/jats:sub>\n                    ) are uniformly integrated on crystalline carbon nitride (CCN), denoted CCN\u2010Pt\n                    <jats:sub>SA+NP<\/jats:sub>\n                    , via photoinduced reduction of chloroplatinic acid. In situ spectroscopic analyses reveal that spatially separated Pt\n                    <jats:sub>SA<\/jats:sub>\n                    \/Pt\n                    <jats:sub>NP<\/jats:sub>\n                    redox pairs enable balanced and rapid photocarrier utilization, yielding closely matched TA\u2010derived decay time constants of photogenerated holes and electrons of 405.1 and 386.7\u00a0ps, respectively. This synchronized charge consumption effectively suppresses recombination. Meanwhile, Pt single\u2010atom sites enhance methanol adsorption and lower the energy barrier for the initial O\u2500H bond cleavage, favoring the generation of alkoxy intermediates. The accelerated hole consumption and proton supply at the oxidation site further facilitate proton\u2010electron coupling reactions on Pt nanoparticles. Consequently, the optimized CCN\u2010Pt\n                    <jats:sub>SA+NP<\/jats:sub>\n                    catalyst delivers exceptional photocatalytic performance, achieving H\n                    <jats:sub>2<\/jats:sub>\n                    and HCHO evolution rates of 24.5 and 22.6\u00a0mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , respectively, with an H\n                    <jats:sub>2<\/jats:sub>\n                    \u2010to\u2010HCHO ratio approaching unity. This work establishes a general strategy for engineering single\u2010atom\/nanoparticle redox pairs to realize matched electron\u2010hole consumption and selective, low\u2010carbon methanol\u2010to\u2010hydrogen conversion.\n                  <\/jats:p>","DOI":"10.1002\/anie.7100046","type":"journal-article","created":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T08:51:02Z","timestamp":1791363062000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Cooperative Shunt Photocatalysis of Pt Single Atoms and Nanoparticles for Efficient Methanol Conversion to Hydrogen and Formaldehyde"],"prefix":"10.1002","author":[{"given":"Youyu","family":"Pang","sequence":"first","affiliation":[{"name":"College of Chemistry Jilin University  Changchun P.R. 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