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Current detoxification strategies predominantly focus on enhancing OH* formation to accelerate CO* oxidation. However, the periodic voltage\/current oscillations induced by accumulated OH species are often overlooked. Such accumulation of secondary poisoning intermediates inevitably leads to a high overpotential and poor operational stability. Herein, guided by machine learning screening, we resolve this dilemma by designing ultrathin PtPdGaRuFeMo high\u2010entropy alloy nanosheets featuring Ga and Ru dual\u2010promoter sites for the bidirectional regulation of CO* and OH* adsorption. Both theoretical analysis and experimental results demonstrate that the synergistic Ga and Ru sites modulate the electronic structure of active centers, balancing the dynamic adsorption of CO* and OH* to mitigate surface poisoning. Consequently, the as\u2010prepared catalysts deliver excellent specific activities of 5.4\u00a0mA\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    for methanol and 3.5\u00a0mA\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    for formic acid electrooxidation, surpassing commercial Pt\/C by factors of 9.7 and 12.8, respectively. This study establishes a dual\u2010promoter bidirectional regulation, providing a promising route offering a robust solution to the stability\u2010activity trade\u2010off in fuel\u2010cell electrocatalysts.\n                  <\/jats:p>","DOI":"10.1002\/anie.7147123","type":"journal-article","created":{"date-parts":[[2026,10,3]],"date-time":"2026-10-03T16:15:21Z","timestamp":1791044121000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Mitigating Surface Poisoning by Bidirectional Regulation for Efficient C1\u2010C2 Molecule Electrooxidation"],"prefix":"10.1002","author":[{"given":"Shuping","family":"Liang","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering University of Jinan  Jinan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yipin","family":"Lv","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering University 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