{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T14:55:29Z","timestamp":1791212129523,"version":"4.1.0"},"reference-count":43,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22108025"],"award-info":[{"award-number":["22108025"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100021171","name":"Basic and Applied Basic Research Foundation of Guangdong Province","doi-asserted-by":"publisher","award":["2025A1515012598"],"award-info":[{"award-number":["2025A1515012598"]}],"id":[{"id":"10.13039\/501100021171","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Selective K\n                    <jats:sup>+<\/jats:sup>\n                    over Li\n                    <jats:sup>+<\/jats:sup>\n                    separation is indispensable for lithium recovery from salt\u2010lake brines, whereas simultaneous high\u2010efficiency separation of K\n                    <jats:sup>+<\/jats:sup>\n                    from interfering Na\n                    <jats:sup>+<\/jats:sup>\n                    and Mg\n                    <jats:sup>2+<\/jats:sup>\n                    cations remains challenging for pristine MOF membranes. Herein, an ultrathin\n                    <jats:italic>b<\/jats:italic>\n                    \u2010oriented Co\u2010gallate MOF membrane is fabricated using a gas\u2013liquid interfacial soft\u2010template approach. The membrane possesses 3D interconnected zigzag subnanochannels (\u22483.7\u00a0\u00c5) that impose geometry\u2010confined ion dehydration, hindering the transport of Li\n                    <jats:sup>+<\/jats:sup>\n                    , Na\n                    <jats:sup>+<\/jats:sup>\n                    , and Mg\n                    <jats:sup>2+<\/jats:sup>\n                    far more significantly than K\n                    <jats:sup>+<\/jats:sup>\n                    , as corroborated by molecular dynamics simulations. Under a concentration gradient driving force, the u\n                    <jats:italic>b<\/jats:italic>\n                    \u2010CoG membrane achieves a prominent K\n                    <jats:sup>+<\/jats:sup>\n                    \/Li\n                    <jats:sup>+<\/jats:sup>\n                    selectivity of 13.5, as well as excellent K\n                    <jats:sup>+<\/jats:sup>\n                    \/Na\n                    <jats:sup>+<\/jats:sup>\n                    and K\n                    <jats:sup>+<\/jats:sup>\n                    \/Mg\n                    <jats:sup>2+<\/jats:sup>\n                    sieving capability. The recorded K\n                    <jats:sup>+<\/jats:sup>\n                    \/Li\n                    <jats:sup>+<\/jats:sup>\n                    selectivity stands as the highest value among MOF ion\u2010sieving membranes. This interfacial orientation strategy provides a promising pathway to advanced ion\u2010sieving membranes for multicomponent industrial brine lithium extraction.\n                  <\/jats:p>","DOI":"10.1002\/anie.7674294","type":"journal-article","created":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T14:34:44Z","timestamp":1791210884000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Ultrathin\n                    <i>b<\/i>\n                    \u2010Oriented Co\u2010Gallate MOF Membranes for Lithium Recovery: Precise Ion Sieving via Geometry\u2010Confined Dehydration"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6274-721X","authenticated-orcid":false,"given":"Yanwei","family":"Sun","sequence":"first","affiliation":[{"name":"Faculty of Arts and Sciences Beijing Normal University  Zhuhai China"},{"name":"Center for Advanced Materials Research Advanced Institute of Natural Sciences Beijing Normal University  Zhuhai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yufan","family":"Yang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering Henan University of Science and Technology  Luoyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0009-7442-1514","authenticated-orcid":false,"given":"Tianhao","family":"Wang","sequence":"additional","affiliation":[{"name":"Faculty of Arts and Sciences Beijing Normal University  Zhuhai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiatong","family":"Shao","sequence":"additional","affiliation":[{"name":"Faculty of Arts and Sciences Beijing Normal University  Zhuhai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiashu","family":"Lu","sequence":"additional","affiliation":[{"name":"Faculty of Arts and Sciences Beijing Normal University  Zhuhai China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,5]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893\u2010024\u201001435\u20102"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44221\u2010022\u201000006\u2010z"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00582K"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s43017\u2010022\u201000387\u20105"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44286\u2010025\u201000250\u20106"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2200751119"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adn0944"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201046378\u20106"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.memsci.2024.123508"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aaq0066"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201063265\u2010w"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202104404"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010022\u201035594\u20107"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s43246\u2010025\u201001045\u20101"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature24044"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201048419\u20106"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.ado7489"},{"key":"e_1_2_8_19_1","doi-asserted-by":"crossref","first-page":"1613","DOI":"10.1016\/j.chempr.2020.06.018","article-title":"Topology Meets Reticular Chemistry for Chemical Separations: MOFs as a Case Study","volume":"6","author":"Bhatt P. M.","year":"2020","journal-title":"Chemistry"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201035970\u2010x"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar100112y"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202115443"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c09466"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202309095"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201808716"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202416628"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00322C"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aay3998"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201027873\u20106"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202307013"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010017\u201000544\u20101"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201054730\u2010z"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202216697"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202311336"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm902032y"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201059188\u20101"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6c03494"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201000857"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202110828"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201064533\u20105"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889811038970"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022\u20101902(60)80092\u20109"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmaterialslett.2c01107"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202101312"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.7674294","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.7674294","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.7674294","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T14:34:45Z","timestamp":1791210885000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.7674294"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,10,5]]},"references-count":43,"alternative-id":["10.1002\/anie.7674294"],"URL":"https:\/\/doi.org\/10.1002\/anie.7674294","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,10,5]]},"assertion":[{"value":"2026-07-26","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-18","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-10-05","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e7674294"}}