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In this study, we report a general in situ silanization platform that enables the integration of organic precursors into silica\u2010based matrices via an aminosilane\u2010mediated \u201cbridge\u201d, yielding monodisperse, size\u2010tunable (10\u223c320\u00a0nm) full\u2010color PNPs with emission spanning blue\u2010purple to red. Aminosilanes with electron\u2010donating characteristics not only promote an intramolecular charge transfer (ICT) state to enhance intersystem crossing (ISC) efficiency but also facilitate the encapsulation of silanized anhydride within silica frameworks (ASLs@SiO\n                    <jats:sub>2<\/jats:sub>\n                    ), effectively shielding the emitters from aqueous and oxygen quenching. Orthogonal screening across 14 anhydrides and 12 aminosilanes validated the strategy's universality, achieving full\u2010color afterglow with a maximum lifetime of 1128.07\u00a0ms and a quantum yield of 24.04%. Furthermore, to precisely control dispersion and size, two distinct ASLs@SiO\n                    <jats:sub>2<\/jats:sub>\n                    architectures were engineered: one embedding silanized anhydride within a concentric silica interlayer, and another infusing it into dendritic porous silica spheres. This scalable, low\u2010cost synthesis (\u223c$1 per 150\u00a0g) underscores the commercial viability of the approach and establishes a new approach for designing high\u2010performance aqueous\u2010phase PNPs.\n                  <\/jats:p>","DOI":"10.1002\/anie.7868412","type":"journal-article","created":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T07:34:30Z","timestamp":1789976070000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Electron\u2010Donating Aminosilane Bridging Enables General Access to Full\u2010Color Aqueous Phosphorescent Nanospheres"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6802-5410","authenticated-orcid":false,"given":"Kang","family":"Shao","sequence":"first","affiliation":[{"name":"College of Chemical Engineering State Key Laboratory of Green Chemical Synthesis and Conversion Zhejiang University of Technology  Hangzhou P. R. 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