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Drawing inspiration from interfacial engineering, we designed a NiPt\u2010Ni(OH)\n                    <jats:sub>2<\/jats:sub>\n                    interface that regulates the local microenvironment, enabling highly efficient hydrogen production from hydrous hydrazine under neutral conditions at room temperature. At the interfaces, strong electronic coupling is established and the adsorption of hydrazine is also altered. The resulting NiPt\u2010Ni(OH)\n                    <jats:sub>2<\/jats:sub>\n                    catalyst achieves a remarkable apparent turnover frequency of 310.7 h\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 298 K, representing the highest performance reported to date for hydrous hydrazine dehydrogenation without external base added during catalysis. Combined spectroscopic analysis and density functional theory calculations reveal that the interfacial Ni(OH)\n                    <jats:sub>2<\/jats:sub>\n                    not only donates electrons to the NiPt alloy, modulating its electronic structure but also provides Br\u00f8nsted basic sites that promote a favorable linear adsorption configuration of hydrazine. This dual electronic and chemical modulation lowers the energy barrier for dehydrogenation and accelerates hydrogen evolution kinetics. Our findings establish a generalizable interface engineering paradigm for catalytic enhancement under mild conditions without relying on external alkaline additives.\n                  <\/jats:p>","DOI":"10.1002\/anie.7897749","type":"journal-article","created":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T07:29:35Z","timestamp":1784273375000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Interface Local\u2010Alkalinity Engineering for Enhanced Dehydrogenation Catalysis in Neutral Media"],"prefix":"10.1002","volume":"65","author":[{"given":"Kun","family":"Wang","sequence":"first","affiliation":[{"name":"Key Laboratory of Green Catalysis of Jiangxi Education Institutes, Key Laboratory of Green Hydrogen and Advanced Catalysis of Jiangxi Province, Key Laboratory of Fluorine and Silicon for Energy Materials and Chemistry of Ministry of Education, Key Laboratory of Energy Catalysis and Conversion of Nanchang 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