{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,17]],"date-time":"2026-10-17T18:40:11Z","timestamp":1792262411214,"version":"4.4.0"},"reference-count":65,"publisher":"Wiley","issue":"43","license":[{"start":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T00:00:00Z","timestamp":1788480000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T00:00:00Z","timestamp":1788480000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100004735","name":"Natural Science Foundation of Hunan Province","doi-asserted-by":"publisher","award":["2026JJ20060"],"award-info":[{"award-number":["2026JJ20060"]}],"id":[{"id":"10.13039\/501100004735","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,10,19]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Organic solar cells (OSCs) based on non\u2010fullerene acceptors have achieved power conversion efficiencies (PCEs) exceeding 20%. However, their long\u2010term stability remains limited by uncontrolled molecular aggregation and morphological degradation in bulk heterojunction (BHJ) films. Here, we report a thiazole\u2010based acceptor (BDTTz) as a molecular packing reshaper that selectively regulates acceptor H\u2010aggregation to enable efficient and stable OSCs. Theoretical calculations reveal stronger interactions between BDTTz and L8\u2010BO than between BDTTz and PM6, enabling targeted reinforcement of acceptor packing without disrupting donor organization. Incorporating BDTTz into PM6:L8\u2010BO blends extends the acceptor crystallization window from 32 to 48\u00a0ms, increases the coherence length from 50.21 to 57.17 \u00c5, and raises the glass\u2010transition temperature from 104\u00b0C to 142\u00b0C, thereby suppressing molecular diffusion and stabilizing the blend morphology. The optimized morphology facilitates charge transport, suppresses the nonradiative recombination, and mitigates the electron\u2013phonon coupling, affording a champion PCE of 20.66% with an extended\n                    <jats:italic>T<\/jats:italic>\n                    <jats:sub>80<\/jats:sub>\n                    lifetime of 1200\u00a0h under continuous illumination and heating conditions. Moreover, BDTTz incorporation into D18:L8\u2010BO blends yields a champion PCE of 21.08%. This work establishes a molecular\u2010level packing\u2010reshaping strategy for developing high\u2010efficiency and long\u2010term\u2010stable OSCs.\n                  <\/jats:p>","DOI":"10.1002\/anie.7970747","type":"journal-article","created":{"date-parts":[[2026,9,4]],"date-time":"2026-09-04T08:34:43Z","timestamp":1788510883000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Regulating H\u2010Aggregation via a Thiazole\u2010Modified Acceptor\u2010Based Packing Reshaper Toward Highly Efficient and Stable Organic Solar Cells"],"prefix":"10.1002","volume":"65","author":[{"given":"Haodong","family":"Huang","sequence":"first","affiliation":[{"name":"School of Physical Sciences Great Bay University  Dongguan Guangdong China"},{"name":"Department of Materials Science and Engineering Southern University of Science and Technology Shenzhen Guangdong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huangyan","family":"Jiang","sequence":"additional","affiliation":[{"name":"School of Electrical Engineering University of South China Hengyang Hunan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0370-1673","authenticated-orcid":false,"given":"Jifa","family":"Wu","sequence":"additional","affiliation":[{"name":"Guangdong Basic Research Center of Excellence for Energy &amp; Information Polymer Materials South China University of Technology  Guangzhou Guangdong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8696-8757","authenticated-orcid":false,"given":"Hanjian","family":"Lai","sequence":"additional","affiliation":[{"name":"School of Electrical Engineering University of South China Hengyang Hunan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-2540-7729","authenticated-orcid":false,"given":"Bin","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Southern University of Science and Technology Shenzhen Guangdong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5967-6887","authenticated-orcid":false,"given":"Yan","family":"Tian","sequence":"additional","affiliation":[{"name":"School of Physical Sciences Great Bay University  Dongguan Guangdong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanfei","family":"Zhao","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Dongguan University of Technology  Dongguan Guangdong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Linsen","family":"Li","sequence":"additional","affiliation":[{"name":"School of Physical Sciences Great Bay University  Dongguan Guangdong China"},{"name":"School of Optoelectronic Engineering Guangdong Polytechnic Normal University  Guangzhou Guangdong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liming","family":"Liu","sequence":"additional","affiliation":[{"name":"Guangdong Basic Research Center of Excellence for Aggregate Science School of Science and Engineering The Chinese University of Hong Kong  Shenzhen Guangdong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qifa","family":"Zheng","sequence":"additional","affiliation":[{"name":"Hunan Zhongyuan Technology Co., Ltd  Hengyang Hunan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuemeng","family":"Yu","sequence":"additional","affiliation":[{"name":"School of Physical Sciences Great Bay University  Dongguan Guangdong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1562-3190","authenticated-orcid":false,"given":"Xiaobin","family":"Peng","sequence":"additional","affiliation":[{"name":"Guangdong Basic Research Center of Excellence for Energy &amp; Information Polymer Materials South China University of Technology  Guangzhou Guangdong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tao","family":"Jia","sequence":"additional","affiliation":[{"name":"School of Optoelectronic Engineering Guangdong Polytechnic Normal University  Guangzhou Guangdong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingcong","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Physical Sciences Great Bay University  Dongguan Guangdong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5962-2128","authenticated-orcid":false,"given":"Chen","family":"Sun","sequence":"additional","affiliation":[{"name":"School of Physical Sciences Great Bay University  Dongguan Guangdong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9966-4357","authenticated-orcid":false,"given":"Jun","family":"Yan","sequence":"additional","affiliation":[{"name":"Guangdong Basic Research Center of Excellence for Aggregate Science School of Science and Engineering The Chinese University of Hong Kong  Shenzhen Guangdong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2553-3017","authenticated-orcid":false,"given":"Chang","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Electrical Engineering University of South China Hengyang Hunan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6193-637X","authenticated-orcid":false,"given":"Xugang","family":"Guo","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Southern University of Science and Technology Shenzhen Guangdong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5496-5858","authenticated-orcid":false,"given":"Sha","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Physical Sciences Great Bay University  Dongguan Guangdong China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,4]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat5063"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11426\u2010021\u20101180\u20106"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11426\u2010022\u20101256\u20108"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202418353"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578\u2010025\u201000792\u20104"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adj3654"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201055924\u20109"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201051359\u2010w"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563\u2010024\u201002062\u20100"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5EE00101C"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010024\u201001557\u2010z"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40843\u2010025\u20103366\u20109"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201066573\u20103"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.73994"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c08124"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202003570"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41566\u2010018\u20100104\u20109"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201046022\u20103"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202302005"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2019.01.004"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010018\u20100181\u20105"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202104552"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201025718\u2010w"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563\u2010022\u201001244\u2010y"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010024\u201001678\u20105"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja900382r"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201037526\u20105"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202508049"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40843\u2010026\u20104210\u20106"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja905980w"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201002367"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2024.01.026"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.154935"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA11146E"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202010856"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2020.02.004"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TC01148E"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201605779"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202107476"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202308863"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201906324"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202500352"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202517029"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.2c02175"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00127"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202518516"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202506445"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201046144\u20108"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.giant.2024.100336"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201707353"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563\u2010026\u201002589\u20104"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202419923"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201801352"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202514047"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41566\u2010023\u201001173\u20105"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202302273"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202516196"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202413309"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE01270K"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563\u2010024\u201002087\u20105"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202513740"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201023975\u20103"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41566\u2010019\u20100573\u20105"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202414080"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5EE00812C"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.7970747","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.7970747","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.7970747","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,17]],"date-time":"2026-10-17T17:40:26Z","timestamp":1792258826000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.7970747"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,4]]},"references-count":65,"journal-issue":{"issue":"43","published-print":{"date-parts":[[2026,10,19]]}},"alternative-id":["10.1002\/anie.7970747"],"URL":"https:\/\/doi.org\/10.1002\/anie.7970747","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,4]]},"assertion":[{"value":"2026-07-08","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-20","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-04","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e7970747"}}