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Selective oxidation to acetate through the C\n                    <jats:sub>2<\/jats:sub>\n                    pathway circumvents CO formation, yet achieving near\u2010exclusive C\n                    <jats:sub>2<\/jats:sub>\n                    selectivity remains challenging. Herein, we report a nitrogen\u2010doping\u2010induced expansion strategy that converts bulk 2H\u2010MoS\n                    <jats:sub>2<\/jats:sub>\n                    into a metastable 1T\u2010rich MoS\n                    <jats:sub>2\u2010x<\/jats:sub>\n                    support (NTMS\n                    <jats:sub>x<\/jats:sub>\n                    ) with enlarged interlayer spacing and abundant sulfur vacancies. Conductive 1T domains preferentially anchor Pd nanoparticles, creating an \u201cisland\u2010sea\u201d architecture that fosters pronounced electronic metal\u2010support interaction (EMSI). Electron transfer from NTMS\n                    <jats:sub>x<\/jats:sub>\n                    to Pd generates electron\u2010rich Pd sites that weaken CO adsorption, while sulfur vacancies enhance hydroxyl adsorption. These synergistic effects steer ethanol electrooxidation toward the C\n                    <jats:sub>2<\/jats:sub>\n                    \u20104e pathway and suppress CO formation. DFT calculations confirm favorable energetics for the C\n                    <jats:sub>2<\/jats:sub>\n                    pathway on Pd\/NTMS\n                    <jats:sub>x<\/jats:sub>\n                    . The catalyst delivers a high current density and 95.7% Faradaic efficiency for acetate of high added value, with no detectable CO intermediates and outstanding durability. In DEFCs, it achieves a maximum power density of 0.68\u00a0W\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and operates stably for over 500 h. This work establishes confined interfacial anchoring on phase\u2010engineered metal dichalcogenides as a rational design principle for achieving high pathway selectivity in multielectron electrocatalysis.\n                  <\/jats:p>","DOI":"10.1002\/anie.7983393","type":"journal-article","created":{"date-parts":[[2026,10,24]],"date-time":"2026-10-24T07:20:01Z","timestamp":1792826401000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Pd Embedded in 1T\u2010Rich MoS\n                    <sub>2<\/sub>\n                    With Island\u2010Sea Confinement for C\n                    <sub>2<\/sub>\n                    \u2010Selective Ethanol Electrooxidation"],"prefix":"10.1002","author":[{"given":"Xiaowen","family":"Gu","sequence":"first","affiliation":[{"name":"Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education Faculty of Chemistry Northeast Normal University  Changchun P. 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