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While this degradation has commonly been addressed through modification of the carbon material itself, the interfacial chemistry that activates carbon oxidation remains poorly understood. Here, we show that the hydrogen\u2010bonding (HB) network of interfacial water strongly influences anodic carbon stability. Operando differential electrochemical mass spectrometry combined with in situ attenuated total reflection surface\u2010enhanced infrared absorption spectroscopy reveals that corrosion accelerates as the interfacial HB network becomes increasingly disrupted, implicating weakly H\u2010bonded water as a reactive water population associated with carbon oxidation. Guided by this mechanistic insight, we modulate the local water structure using ionomer\u2010defined interfaces. In a case study of chlorine evolution on a carbon\u2010supported single\u2010atom Pt catalyst, Sustainion\u2010defined interfaces preserve a more ordered interfacial water\u2010network and suppress carbon corrosion relative to Nafion\u2010defined interfaces, whereas the latter promote surface charging favorable for chlorine evolution kinetics. By combining these functions in a mixed\u2010ionomer layer, water\u2010network\u2010guided stabilization is implemented under anodic electrocatalytic operation with suppressed carbon corrosion. This work highlights interfacial water\u2010network modulation as a promising design principle for extending the anodic stability of carbon\u2010based electrodes.<\/jats:p>","DOI":"10.1002\/anie.8140389","type":"journal-article","created":{"date-parts":[[2026,10,24]],"date-time":"2026-10-24T07:06:36Z","timestamp":1792825596000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Interfacial Water\u2010Networks Regulate the Anodic Stability of Carbon Electrodes"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4875-0287","authenticated-orcid":false,"given":"Junsic","family":"Cho","sequence":"first","affiliation":[{"name":"Department of Chemistry Pohang University of Science and Technology (POSTECH)  Pohang Republic of 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