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Herein, we report the bottom\u2010up construction of colloidal supraparticles (SPs) comprising photocatalytic CdS\u2010based and plasmonic Au nanoparticles (NPs), forming spatially ordered hybrid superstructures with tunable Au NP size and compositional ratios. The optimized CdSe@CdS\u2010Au SPs achieve a hydrogen evolution rate of 160\u00a0mmol h\n                    <jats:sup>\u22121<\/jats:sup>\n                    g\n                    <jats:sup>\u22121<\/jats:sup>\n                    under visible light, representing a significant enhancement over the mixture of the same components and outperforming previously reported similar NP\u2010based systems. Ultrafast spectroscopic analyses combined with finite element simulations reveal that spatial confinement facilitates plasmon\u2010mediated interactions between Au and CdSe@CdS NPs, leading to enhanced plasmonic local electric fields and efficient plasmon\u2010induced resonance energy transfer from Au to the semiconductor domains. These photophysical advantages collectively account for the markedly improved photocatalytic activity. This study demonstrates nanoscale spatial engineering as a versatile strategy for tailoring hybrid architectures toward high\u2010efficiency solar\u2010to\u2010chemical energy conversion.\n                  <\/jats:p>","DOI":"10.1002\/anie.8359659","type":"journal-article","created":{"date-parts":[[2026,4,27]],"date-time":"2026-04-27T07:17:06Z","timestamp":1777274226000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Engineering Plasmon\u2010Semiconductor Coupling in Spatially Ordered Supraparticles for Boosted Photocatalytic Hydrogen Evolution"],"prefix":"10.1002","volume":"65","author":[{"given":"Wenlong","family":"Fu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Porous Metal Materials Shaanxi International Research Center for Soft Matter School of Materials Science and Engineering Xi'an Jiaotong University Xi'an PR 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