{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T22:50:07Z","timestamp":1792795807728,"version":"4.5.0"},"reference-count":44,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2026,2,9]],"date-time":"2026-02-09T00:00:00Z","timestamp":1770595200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"},{"start":{"date-parts":[[2026,2,9]],"date-time":"2026-02-09T00:00:00Z","timestamp":1770595200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U22A20147"],"award-info":[{"award-number":["U22A20147"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22261142666"],"award-info":[{"award-number":["22261142666"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["51932007"],"award-info":[{"award-number":["51932007"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22238009"],"award-info":[{"award-number":["22238009"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22361142704"],"award-info":[{"award-number":["22361142704"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52502372"],"award-info":[{"award-number":["52502372"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012152","name":"National Postdoctoral Program for Innovative Talents","doi-asserted-by":"publisher","award":["BX20240341"],"award-info":[{"award-number":["BX20240341"]}],"id":[{"id":"10.13039\/501100012152","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004837","name":"Ministerio de Ciencia e Innovaci\u00f3n","doi-asserted-by":"publisher","award":["PRE2022\u2010102036"],"award-info":[{"award-number":["PRE2022\u2010102036"]}],"id":[{"id":"10.13039\/501100004837","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004837","name":"Ministerio de Ciencia e Innovaci\u00f3n","doi-asserted-by":"publisher","award":["CEX\u20102021\u2010001230\u2010S"],"award-info":[{"award-number":["CEX\u20102021\u2010001230\u2010S"]}],"id":[{"id":"10.13039\/501100004837","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004837","name":"Ministerio de Ciencia e Innovaci\u00f3n","doi-asserted-by":"publisher","award":["PID2024\u2010161014NB\u2010I00"],"award-info":[{"award-number":["PID2024\u2010161014NB\u2010I00"]}],"id":[{"id":"10.13039\/501100004837","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003359","name":"Generalitat Valenciana","doi-asserted-by":"publisher","award":["CIPROM\/2024\/071"],"award-info":[{"award-number":["CIPROM\/2024\/071"]}],"id":[{"id":"10.13039\/501100003359","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003359","name":"Generalitat Valenciana","doi-asserted-by":"publisher","award":["MFA\/2022\/023"],"award-info":[{"award-number":["MFA\/2022\/023"]}],"id":[{"id":"10.13039\/501100003359","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,3,16]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The rational design of heterostructured photocatalysts that simultaneously enable efficient carrier separation, photothermal synergy, and controllable reaction pathways is crucial for advancing CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion. Here, a Ni\/Ti\n                    <jats:sub>3<\/jats:sub>\n                    C\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>x<\/jats:sub>\n                    MXene heterojunction is synthesized via Lewis acid molten\u2010salt etching, featuring ultrathin Ni platelets strongly anchored to the MXene substrate through interfacial TiNi\n                    <jats:sub>3<\/jats:sub>\n                    bonding. This architecture establishes an S\u2010scheme charge transfer pathway, as evidenced by in situ irradiated X\u2010ray photoelectron and X\u2010ray absorption spectroscopy, which confirm efficient carrier transfer and separation, while femtosecond transient absorption spectroscopy reveals ultrafast interfacial dynamics. Under photothermal conditions, the cooperative interplay of metallic Ni, surface NiO\n                    <jats:sub>x<\/jats:sub>\n                    , and the conductive MXene substrate couples directional charge migration with thermally assisted molecular activation and barrier lowering, thereby enabling regulated CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation product distribution between CH\n                    <jats:sub>4<\/jats:sub>\n                    and CH\n                    <jats:sub>3<\/jats:sub>\n                    OH. Density functional theory demonstrates that surface\u2010state evolution, rather than simple oxidation degree, modulates adsorption energetics and alters the relative barriers of CH\n                    <jats:sub>4<\/jats:sub>\n                    and CH\n                    <jats:sub>3<\/jats:sub>\n                    OH pathways, such that moderately oxidized Ni\u2013NiO\n                    <jats:sub>x<\/jats:sub>\n                    interfacial ensembles favour methanol forming intermediates, whereas extensive oxidation suppresses CH\n                    <jats:sub>3<\/jats:sub>\n                    OH formation. Collectively, these findings demonstrate a robust strategy for exploiting MXene\u2010based heterojunction interfaces in photothermal catalysis and underscore the pivotal role of surface state regulated reaction pathways in steering product distribution during CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation.\n                  <\/jats:p>","DOI":"10.1002\/anie.8425918","type":"journal-article","created":{"date-parts":[[2026,2,10]],"date-time":"2026-02-10T04:54:56Z","timestamp":1770699296000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["Surface\u2010State\u2013Regulated Product Distribution in Photothermal CO\n                    <sub>2<\/sub>\n                    Hydrogenation Over MXene\u2010Based S\u2010Scheme Catalyst"],"prefix":"10.1002","volume":"65","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7296-578X","authenticated-orcid":false,"given":"Dawid D.","family":"Kruger","sequence":"first","affiliation":[{"name":"Instituto de Tecnolog\u00eda Qu\u00edmica, Consejo Superior de Investigaciones Cient\u00edficas\u2010Universitat Polit\u00e8cnica de Valencia Universitat Polit\u00e8cnica de Valencia  Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2333-548X","authenticated-orcid":false,"given":"Mar\u00eda","family":"Cabrero\u2010Antonino","sequence":"additional","affiliation":[{"name":"Instituto de Tecnolog\u00eda Qu\u00edmica, Consejo Superior de Investigaciones Cient\u00edficas\u2010Universitat Polit\u00e8cnica de Valencia Universitat Polit\u00e8cnica de Valencia  Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8541-1914","authenticated-orcid":false,"given":"Silvio","family":"Osella","sequence":"additional","affiliation":[{"name":"Chemical and Biological Systems Simulation Lab Centre of New Technologies University of Warsaw  Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5763-128X","authenticated-orcid":false,"given":"Feiyan","family":"Xu","sequence":"additional","affiliation":[{"name":"Laboratory of Solar Fuel Faculty of Materials Science and Chemistry China University of Geosciences  Wuhan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0612-8633","authenticated-orcid":false,"given":"Jiaguo","family":"Yu","sequence":"additional","affiliation":[{"name":"Laboratory of Solar Fuel Faculty of Materials Science and Chemistry China University of Geosciences  Wuhan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9205-2278","authenticated-orcid":false,"given":"Ana","family":"Primo","sequence":"additional","affiliation":[{"name":"Instituto de Tecnolog\u00eda Qu\u00edmica, Consejo Superior de Investigaciones Cient\u00edficas\u2010Universitat Polit\u00e8cnica de Valencia Universitat Polit\u00e8cnica de Valencia  Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9664-493X","authenticated-orcid":false,"given":"Hermenegildo","family":"Garcia","sequence":"additional","affiliation":[{"name":"Instituto de Tecnolog\u00eda Qu\u00edmica, Consejo Superior de Investigaciones Cient\u00edficas\u2010Universitat Polit\u00e8cnica de Valencia Universitat Polit\u00e8cnica de Valencia  Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,2,9]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201904256"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s43586\u2010023\u201000243\u2010w"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202414672"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.3390\/ma10060629"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201049004\u20107"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC07144G"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c00478"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4TA03676J"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00357C"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c11625"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201601657"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202504167"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2024.123822"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202501285"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201102306"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.9b06394"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41699\u2010021\u201000239\u20108"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00324F"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/elt2.17"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/admi.202100975"},{"key":"e_1_2_7_22_1","doi-asserted-by":"crossref","unstructured":"T.HaneefK.Rasool J.Iqbal et\u00a0al. \u201cRecent progress in two dimensional Mxenes for photocatalysis: a critical review 2D Mater \u201d10 no.1(2023):012001.","DOI":"10.1088\/2053-1583\/ac9e66"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2023.02.104"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/smtd.202300063"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceja.2024.100593"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.123316"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jiec.2022.01.030"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2022.155850"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202405453"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202002602"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.1c00990"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010020\u201018350\u20107"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202313513"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b00574"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563\u2010020\u20100657\u20100"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202307106"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010018\u20100067\u20108"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4QI01280A"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtnano.2022.100283"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevResearch.2.033516"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570\u2010025\u201000698\u20103"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c00827"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2018.04.060"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201307851"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.0c00857"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.8425918","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.8425918","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.8425918","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,20]],"date-time":"2026-03-20T09:52:04Z","timestamp":1774000324000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.8425918"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,2,9]]},"references-count":44,"journal-issue":{"issue":"12","published-print":{"date-parts":[[2026,3,16]]}},"alternative-id":["10.1002\/anie.8425918"],"URL":"https:\/\/doi.org\/10.1002\/anie.8425918","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,2,9]]},"assertion":[{"value":"2025-12-07","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-01-24","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-02-09","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e8425918"}}