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Chiral and magnetic catalysts selectively transmit spin\u2010compatible carriers, whereas non\u2010polarized light generates mixed\u2010spin populations, limiting carrier utilization. Herein, we demonstrate that circularly polarized light (CPL) reversibly modulates spin\u2010dependent carrier transport in Ni\u2010cocatalyst\u2010decorated, cysteine\u2010modified CdS nanorods, thereby promoting spin\u2010sensitive carrier utilization during aqueous methanol reforming. Optimized D(\u2212)\u2010CdS\/Ni exhibits a 71.1% higher hydrogen evolution rate under left\u2010handed CPL (LCP) than under right\u2010handed CPL (RCP) at identical light intensity and spectrum, achieving an apparent quantum efficiency of 74.4% at 420\u00a0nm while promoting methanol oxidation toward formic acid. CPL\u2010coupled magnetic conductive atomic force microscopy reveals that LCP increases the apparent spin polarization from 70.9% in the dark to 89.1%, whereas RCP suppresses it to 12.8%. Spin\u2010polarized calculations identify nonequivalent electronic channels, while spectroscopic and kinetic measurements support enhanced carrier extraction and reduced recombination under LCP. Together, these findings establish photon handedness as a reversible optical variable for modulating spin\u2010selective transport and photoredox chemistry, offering a strategy to complement material\u2010encoded spin filtering with dynamic optical control of carrier utilization.<\/jats:p>","DOI":"10.1002\/anie.8457661","type":"journal-article","created":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T13:18:38Z","timestamp":1792070318000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Circularly Polarized Light Amplifies Spin Polarization for Efficient Photoredox Chemistry in a Chiral Magnetic Catalyst"],"prefix":"10.1002","author":[{"given":"Shuaikun","family":"Ji","sequence":"first","affiliation":[{"name":"Beijing Key Laboratory of Intelligent Molecular Materials and High\u2010throughput Manufacturing, School of Chemistry and Chemical Engineering Beijing Institute of Technology  Beijing China"},{"name":"State Key Laboratory of Environment Characteristics and Effects for Near\u2010space, School of Interdisciplinary Sciences Beijing Institute of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiahong","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Environment Characteristics and Effects for Near\u2010space, School of Interdisciplinary Sciences Beijing Institute of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui","family":"Ai","sequence":"additional","affiliation":[{"name":"Office of National Assets &amp; Laboratory Management Beijing Institute of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qingli","family":"Wang","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory of Intelligent Molecular Materials and High\u2010throughput Manufacturing, School of Chemistry and Chemical Engineering Beijing Institute of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Caiwei","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Environment Characteristics and Effects for Near\u2010space, School of Interdisciplinary Sciences Beijing Institute of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junting","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Environment Characteristics and Effects for Near\u2010space, School of Interdisciplinary Sciences Beijing Institute of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6475-8839","authenticated-orcid":false,"given":"Xianghong","family":"Niu","sequence":"additional","affiliation":[{"name":"School of Science Nanjing University of Posts &amp; Telecommunications  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7414-4902","authenticated-orcid":false,"given":"Jiatao","family":"Zhang","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory of Intelligent Molecular Materials and High\u2010throughput Manufacturing, School of Chemistry and Chemical Engineering Beijing Institute of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8702-5304","authenticated-orcid":false,"given":"Yiou","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Environment Characteristics and Effects for Near\u2010space, School of Interdisciplinary Sciences Beijing Institute of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,15]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c01204"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00201"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.1c02516"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CS00317A"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5CS00239G"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b12971"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1199339"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.3c00661"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.63.104425"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c10526"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202319920"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.5c02365"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202517047"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/b704636g"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja902800f"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.8b02752"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4049"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2019.118233"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/la800964s"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.5c02716"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b01830"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.6b01880"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.2c01953"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1088\/1367\u20102630\/14\/5\/053050"},{"key":"e_1_2_8_26_1","doi-asserted-by":"crossref","unstructured":"J. H.Poynting \u201cThe Wave Motion of a Revolving Shaft and a Suggestion as to the Angular Momentum in a Beam of Circularly Polarised Light \u201dProceedings of the Royal Society of London. 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