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However, the controllable modulation of catalyst structures to construct an effective anti\u2010chlorine protective layer, one that simultaneously enhances both Cl corrosion resistance and anodic oxidation reaction activity, remains a formidable challenge. Herein, we report a phosphonyl\u2010ligand engineering strategy that promotes the transformation of metal\u2013organic frameworks (MOFs) into metal oxyhydroxides containing oxygen\u2010anions during alkaline seawater ethanol oxidation reaction (EOR) with enhanced activity and Cl\n                    <jats:sup>\u2013<\/jats:sup>\n                    corrosion resistance. Leveraging the tunable nature of organic ligands in MOFs provides a versatile platform for the in situ formation of oxygen anion layers with robust chlorine corrosion resistance. A phosphorus\u2010containing MOF (P\n                    <jats:sub>a<\/jats:sub>\n                    \u2010Ni\u2010TPA) was synthesized by partially substituting terephthalic acid (TPA) with 4\u2010phosphonobenzoic acid (P\n                    <jats:sub>a<\/jats:sub>\n                    ). In contrast to the conventional MOF (Ni\u2010TPA), the in situ generated metal oxyhydroxide from P\n                    <jats:sub>a<\/jats:sub>\n                    \u2010Ni\u2010TPA incorporates PO\n                    <jats:sub>4<\/jats:sub>\n                    <jats:sup>3\u2013<\/jats:sup>\n                    . PO\n                    <jats:sub>4<\/jats:sub>\n                    <jats:sup>3\u2013<\/jats:sup>\n                    promotes the adsorption of ethanol and its intermediates onto nickel centers while inhibiting Cl adsorption, thereby significantly boosting both EOR activity and Cl corrosion resistance. These findings establish a detailed structure\u2010performance correlation between MOF structural evolution and both catalytic activity toward alkaline seawater EOR and resistance to chlorine corrosion.\n                  <\/jats:p>","DOI":"10.1002\/anie.8462106","type":"journal-article","created":{"date-parts":[[2026,6,15]],"date-time":"2026-06-15T11:07:14Z","timestamp":1781521634000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Phosphoryl\u2010Engineered MOFs Promote Interfacial Reconstruction for Efficient Seawater Ethanol Electrooxidation"],"prefix":"10.1002","volume":"65","author":[{"given":"Jieting","family":"Ding","sequence":"first","affiliation":[{"name":"School of Materials and Energy of Lanzhou University  Lanzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tingyu","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Materials and Energy of Lanzhou University  Lanzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liu","family":"Zhu","sequence":"additional","affiliation":[{"name":"Electron Microscopy Centre of Lanzhou University  Lanzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bowen","family":"Shi","sequence":"additional","affiliation":[{"name":"School of Materials and Energy of Lanzhou University  Lanzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Hu","sequence":"additional","affiliation":[{"name":"School of Materials and Energy of Lanzhou University  Lanzhou China"},{"name":"Electron Microscopy Centre of Lanzhou University  Lanzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1527-551X","authenticated-orcid":false,"given":"Yingwei","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6980-4694","authenticated-orcid":false,"given":"Yong","family":"Peng","sequence":"additional","affiliation":[{"name":"School of Materials and Energy of Lanzhou University  Lanzhou China"},{"name":"Electron Microscopy Centre of Lanzhou University  Lanzhou 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