{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T04:04:47Z","timestamp":1789531487726,"version":"build-2803163510"},"reference-count":52,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T00:00:00Z","timestamp":1789430400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T00:00:00Z","timestamp":1789430400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2024YFA1509901"],"award-info":[{"award-number":["2024YFA1509901"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Nickel\u2010based catalysts are promising for dry reforming of methane (DRM) owing to their high C\u2500H bond activation ability and low cost, while highly susceptible to coke deposition and sintering. Here, we report a heteroenergetic Ce\n                    <jats:sub>0.75<\/jats:sub>\n                    Ti\n                    <jats:sub>0.25<\/jats:sub>\n                    O\n                    <jats:sub>2\u2010x<\/jats:sub>\n                    support that simultaneously regulates Ni nanoparticle stabilization, DRM activity, and oxygen\u2010mediated carbon removal. Neural\u2010network\u2010based molecular dynamics (NN\u2010MD) simulations and electron microscopy show that partial Ti substitution in CeO\n                    <jats:sub>2<\/jats:sub>\n                    transforms the strong Ni\u2010CeO\n                    <jats:sub>2<\/jats:sub>\n                    interaction and weak Ni\u2010TiO\n                    <jats:sub>2<\/jats:sub>\n                    interaction into an intermediate wetting regime with a Ni\u2010support contact angle close to 90\u00b0, suppressing both particle migration\/coalescence\u2010 and Ostwald ripening\u2010induced sintering while preserving a coupled population of active interfacial and metallic Ni sites. Characterizations and Bader charge analysis further reveal that Ce\n                    <jats:sub>0.75<\/jats:sub>\n                    Ti\n                    <jats:sub>0.25<\/jats:sub>\n                    O\n                    <jats:sub>2\u2010x<\/jats:sub>\n                    moderates Ni\u2010support electronic coupling and improves oxygen vacancy concentration and lattice oxygen mobility. These coupled structural and chemical effects facilitate methane activation and transient carbon removal through synergistic Mars\u2010van Krevelen and Langmuir\u2010Hinshelwood pathways. As a result, Ni\/Ce\n                    <jats:sub>0.75<\/jats:sub>\n                    Ti\n                    <jats:sub>0.25<\/jats:sub>\n                    O\n                    <jats:sub>2\u2010x<\/jats:sub>\n                    achieves highly competitive DRM performance with near\u2010equilibrium CH\n                    <jats:sub>4<\/jats:sub>\n                    and CO\n                    <jats:sub>2<\/jats:sub>\n                    conversions of 93.8% and 94.3%, respectively, at 750\u00b0C and remains stable over 120\u00a0h without noticeable deactivation. This work establishes heteroenergetic support engineering as an effective strategy that reconciles high activity with long\u2010term stability in thermally demanding catalytic reactions.\n                  <\/jats:p>","DOI":"10.1002\/anie.8581956","type":"journal-article","created":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T03:18:11Z","timestamp":1789528691000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Breaking the Activity\u2010Stability Trade\u2010Off in Dry Reforming of Methane via Heteroenergetic Support Engineering"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0005-1603-1666","authenticated-orcid":false,"given":"Mengyao","family":"Bao","sequence":"first","affiliation":[{"name":"Global College Shanghai Jiao Tong University Shanghai 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