{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,5]],"date-time":"2026-11-05T17:41:33Z","timestamp":1793900493308,"version":"4.8.0"},"reference-count":49,"publisher":"Wiley","issue":"37","license":[{"start":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T00:00:00Z","timestamp":1783382400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T00:00:00Z","timestamp":1783382400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52472262"],"award-info":[{"award-number":["52472262"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,9,7]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Electrocatalytic urea synthesis from carbon dioxide (CO\n                    <jats:sub>2<\/jats:sub>\n                    ) and nitrate (NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) offers an alternative to the energy\u2010intensive Bosch\u2010Meiser process but is limited by poor selectivity and Faradaic efficiency (FE). Herein, we proposed a defect engineering strategy by constructing ordered Cu nanowire electrocatalysts enriched with abundant twin boundaries (TBs) that can drive spatial proximity between the key intermediates derived from asymmetric activation of CO\n                    <jats:sub>2<\/jats:sub>\n                    and optimized adsorption of NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    . Specifically, it could achieve a high FE of 61.81% and a peak yield rate of 5.80\u00a0mg h\n                    <jats:sup>\u22121<\/jats:sup>\n                    cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    for urea production under a three\u2010electrode configuration. The\n                    <jats:styled-content>underlying<\/jats:styled-content>\n                    mechanism can be described as the TB\u2010induced compression shortening the Cu\u2013Cu bond, creating Cu\n                    <jats:sub>2<\/jats:sub>\n                    \u2010pair pockets that geometrically matched CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption and enabled asymmetric activation to *CO, further strengthening Cu \u2192 CO \u03c0 back\u2010donation and building a *CO reservoir. Smoluchowski smoothing rendered ridge Cu sites electron\u2010deficient, enriching NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    near Cu\n                    <jats:sub>2<\/jats:sub>\n                    \u2010pair pockets for C\u2013N coupling.\n                  <\/jats:p>","DOI":"10.1002\/anie.8722468","type":"journal-article","created":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T18:46:51Z","timestamp":1783450011000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Twin\u2010Boundary Cu\n                    <sub>2<\/sub>\n                    \u2010Pair Pockets Drive Spatial Proximity of Key Intermediates for Efficient Urea Electrosynthesis"],"prefix":"10.1002","volume":"65","author":[{"given":"Mingyu","family":"Cheng","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China  Hefei Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shao","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China  Hefei Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bocheng","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China  Hefei Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanxu","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China  Hefei Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yifan","family":"Wu","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China  Hefei Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenghua","family":"Duan","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China  Hefei Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zechuan","family":"Dai","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China  Hefei Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Buqi","family":"Ke","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China  Hefei Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6092-1344","authenticated-orcid":false,"given":"Jing","family":"Xia","sequence":"additional","affiliation":[{"name":"Key Laboratory of Photochemical Conversion and Optoelectronic Materials Technical Institute of Physics and Chemistry Chinese Academy of Sciences Beijing People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4887-536X","authenticated-orcid":false,"given":"Genqiang","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China  Hefei Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0526-5473","authenticated-orcid":false,"given":"Fuqiang","family":"Huang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Artificial Intelligent Creation Extreme Energy Materials of the Ministry of Education, State Key Lab of Metal Matrix Composites, School of Materials Science and Engineering Shanghai Jiao Tong University Shanghai People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,7]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010022\u201033066\u20106"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CS00381C"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010023\u201000951\u20102"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202413774"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202307123"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.2c01177"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.3c03047"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202202604"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893\u2010024\u201001302\u20100"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202300020"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201044131\u2010z"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201050499\u20103"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202410938"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202315324"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7EE01571B"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/srep17729"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.8b12584"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2022.165293"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2EE01334G"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201915992"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c01562"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c03830"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201042794\u20102"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201047025\u2010w"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202509834"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c04483"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c15109"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2020.12.025"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201040273\u20102"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c09805"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202413534"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202201500"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11426\u2010023\u20101524\u20104"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.3c00824"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.xcrp.2021.100378"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2020.05.014"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202505211"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202501886"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c00583"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893\u2010021\u201000741\u20103"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202507869"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202503424"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202418828"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp052961b"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010023\u201001020\u20104"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1006652108"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2017.11.021"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201901396"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b11291"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.8722468","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.8722468","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.8722468","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T13:13:50Z","timestamp":1788786830000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.8722468"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,7]]},"references-count":49,"journal-issue":{"issue":"37","published-print":{"date-parts":[[2026,9,7]]}},"alternative-id":["10.1002\/anie.8722468"],"URL":"https:\/\/doi.org\/10.1002\/anie.8722468","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,7]]},"assertion":[{"value":"2026-03-01","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-06-18","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-07","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e8722468"}}