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Combining reversible reconfiguration with efficient sequential energy transfer remains challenging. Herein, we report reconfigurable Ir(III) complex\u2010based co\u2010assemblies for sequential energy transfer and programmable luminescence. In H\n                    <jats:sub>2<\/jats:sub>\n                    O\/CH\n                    <jats:sub>3<\/jats:sub>\n                    CN with a 90% water content,\n                    <jats:bold>Ir\u2010D<\/jats:bold>\n                    self\u2010assembles into blue\u2010phosphorescent nanorods. Co\u2010assembly of\n                    <jats:bold>Ir\u2010D<\/jats:bold>\n                    with erythrosine Y (\n                    <jats:bold>A1<\/jats:bold>\n                    ) or Nile red (\n                    <jats:bold>A2<\/jats:bold>\n                    ) enables one\u2010step energy transfer, whereas co\u2010assembly with both acceptors enables two\u2010step sequential energy transfer with 84.8% efficiency and 88.7% photoluminescence quantum yield. Notably, only 0.1 mol%\n                    <jats:bold>A2<\/jats:bold>\n                    affords white\u2010light emission with CIE coordinates of (0.31, 0.34), reflecting efficient acceptor\u2010emission amplification. Beyond composition\u2010dependent tuning, the donor\u2013acceptor co\u2010assemblies can be reconstructed after formation: heating dissociates the assemblies, and adding or adjusting\n                    <jats:bold>A1<\/jats:bold>\n                    and\n                    <jats:bold>A2<\/jats:bold>\n                    in the dissociated state produces new co\u2010assemblies upon cooling, changing the emission from white to yellow and then red. The thermally controlled switching of energy transfer is further used for multicolor information encryption and molecular logic operations. This work shows that supramolecular dynamics can move ALHSs beyond static donor\u2013acceptor construction by allowing energy transfer and luminescence to be reconfigured after co\u2010assembly.\n                  <\/jats:p>","DOI":"10.1002\/anie.8728174","type":"journal-article","created":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T04:04:57Z","timestamp":1790654697000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Dynamically Reconfigurable Ir(III) Complex\u2010Based Co\u2010Assemblies for Sequential Energy Transfer and Programmable Luminescence"],"prefix":"10.1002","author":[{"given":"Chengshuai","family":"Shao","sequence":"first","affiliation":[{"name":"Cancer Hospital of Dalian University of Technology State Key Laboratory of Fine Chemicals, Frontier Science Center For Smart Materials, School of Chemical Engineering Dalian University of Technology  Dalian 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3521-8483","authenticated-orcid":false,"given":"Chun","family":"Liu","sequence":"additional","affiliation":[{"name":"Cancer Hospital of Dalian University of Technology State Key Laboratory of Fine Chemicals, Frontier Science Center For Smart Materials, School of Chemical Engineering Dalian University of Technology  Dalian 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