{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T13:47:21Z","timestamp":1791899241957,"version":"4.3.4"},"reference-count":38,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T00:00:00Z","timestamp":1791849600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T00:00:00Z","timestamp":1791849600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["T2422028"],"award-info":[{"award-number":["T2422028"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52473270"],"award-info":[{"award-number":["52473270"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["12234005"],"award-info":[{"award-number":["12234005"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["T2321002"],"award-info":[{"award-number":["T2321002"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2024YFA1207900\uff1a2022YFA1203304"],"award-info":[{"award-number":["2024YFA1207900\uff1a2022YFA1203304"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004608","name":"Natural Science Foundation of Jiangsu Province","doi-asserted-by":"publisher","award":["BK20231411"],"award-info":[{"award-number":["BK20231411"]}],"id":[{"id":"10.13039\/501100004608","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Aqueous aluminum\u2010ion batteries (AAIBs) are compelling for sustainable storage, yet the strong hydrolysis of Al\n                    <jats:sup>3+<\/jats:sup>\n                    acidifies the electrolyte, causing corrosion and passivation that necessitate modification. Additives designed to break the rigid Al\n                    <jats:sup>3+<\/jats:sup>\n                    solvation shell face a paradox: they often compromise reversibility via either dielectric collapse or kinetic deadlocks. Here, we break this paradox by establishing a weak\u2010coordination asymmetric electrolyte based on aluminum trifluoromethanesulfonate (Al(OTF)\n                    <jats:sub>3<\/jats:sub>\n                    ), dimethyl sulfoxide (DMSO), and fluoroethylene carbonate (FEC). DMSO coordinates to Al\n                    <jats:sup>3+<\/jats:sup>\n                    , displacing coordinated water to suppress water activity, but cannot preserve the dielectric environment. FEC compensates via three synergistic functions: high dielectric constant for electrostatic screening, weak hydrogen bonding for solvation asymmetry reinforcement, and reductive decomposition for solid electrolyte interphase(SEI) formation. The sequential coupling of DMSO\u2010mediated solvation disruption with FEC\u2010enables dielectric\/interfacial compensation accelerates desolvation and stabilizes electrode: a fluorinated SEI enables 2000\u00a0h reversible Al plating\/stripping, while a spinel\u2010to\u2010layer transformation creates a fluorinated interface on vanadium oxide with asymmetric channels, mitigating dissolution. The full cell retains 90.8% capacity after 2000 cycles at 4 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . By showing that resolving one bottleneck can expose another, this work reframes additive optimization as sequential processes of identifying and compensating coupled failure mechanisms, generalizing a design principle for multivalent aqueous electrolytes.\n                  <\/jats:p>","DOI":"10.1002\/anie.8801354","type":"journal-article","created":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T13:00:33Z","timestamp":1791896433000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Breaking the Additive Paradox in Aqueous Aluminum\u2010Ion Batteries via Weak\u2010Coordination Asymmetric Electrolyte Chemistry"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0008-9283-5991","authenticated-orcid":false,"given":"Rui","family":"Pan","sequence":"first","affiliation":[{"name":"SEU\u2010FEI Nano\u2010Pico Center Key Laboratory of MEMS of Ministry of Education Southeast University  Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qizhen","family":"Zhu","sequence":"additional","affiliation":[{"name":"SEU\u2010FEI Nano\u2010Pico Center Key Laboratory of MEMS of Ministry of Education Southeast University  Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chen","family":"Li","sequence":"additional","affiliation":[{"name":"SEU\u2010FEI Nano\u2010Pico Center Key Laboratory of MEMS of Ministry of Education Southeast University  Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7533-3251","authenticated-orcid":false,"given":"Andreu","family":"Cabot","sequence":"additional","affiliation":[{"name":"Catalonia Energy Research Institute\u2010IREC Sant Adri\u00e0 de Bes\u00f2s ICREA Pg. Lluis Companys 23  Barcelona Catalonia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6751-9275","authenticated-orcid":false,"given":"Bowen","family":"Jiang","sequence":"additional","affiliation":[{"name":"SEU\u2010FEI Nano\u2010Pico Center Key Laboratory of MEMS of Ministry of Education Southeast University  Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anqi","family":"Zheng","sequence":"additional","affiliation":[{"name":"SEU\u2010FEI Nano\u2010Pico Center Key Laboratory of MEMS of Ministry of Education Southeast University  Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiaxin","family":"Shen","sequence":"additional","affiliation":[{"name":"SEU\u2010FEI Nano\u2010Pico Center Key Laboratory of MEMS of Ministry of Education Southeast University  Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenjing","family":"Jiang","sequence":"additional","affiliation":[{"name":"SEU\u2010FEI Nano\u2010Pico Center Key Laboratory of MEMS of Ministry of Education Southeast University  Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-9874-1385","authenticated-orcid":false,"given":"Guoju","family":"Zhang","sequence":"additional","affiliation":[{"name":"SEU\u2010FEI Nano\u2010Pico Center Key Laboratory of MEMS of Ministry of Education Southeast University  Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shulin","family":"Jiao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Information Photonics and Optical Communications &amp; Beijing Key Laboratory of Information Metamaterials School of Physical Science and Technology Beijing University of Posts and Telecommunications  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"YingYu","family":"Han","sequence":"additional","affiliation":[{"name":"Key Laboratory of Multifunctional Nanomaterials and Smart Systems Suzhou Institute of Nano\u2010Tech and Nano\u2010Bionics Chinese Academy of Sciences  Suzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2750-5004","authenticated-orcid":false,"given":"Litao","family":"Sun","sequence":"additional","affiliation":[{"name":"SEU\u2010FEI Nano\u2010Pico Center Key Laboratory of MEMS of Ministry of Education Southeast University  Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5268-6807","authenticated-orcid":false,"given":"Kuibo","family":"Yin","sequence":"additional","affiliation":[{"name":"SEU\u2010FEI Nano\u2010Pico Center Key Laboratory of MEMS of Ministry of Education Southeast University  Nanjing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1627-3946","authenticated-orcid":false,"given":"Qichong","family":"Zhang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Multifunctional Nanomaterials and Smart Systems Suzhou Institute of Nano\u2010Tech and Nano\u2010Bionics Chinese Academy of Sciences  Suzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,13]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010026\u201010174\u20107"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/nenergy.2017.108"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010024\u201008465\u2010y"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2085"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010020\u201000728\u2010y"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201601357"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adl5482"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aao7233"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aef4850"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1080\/03067318408076961"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010022\u201004983\u20109"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature14340"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.abg6314"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/smtd.202300758"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.261.5124.1029"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c04820"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2EE23237H"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201915107"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.9b14578"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202014150"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010018\u201007980\u20107"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c05054"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565\u2010023\u201001367\u20106"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1212741"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/451652a"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2024.103772"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c11111"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563\u2010020\u20100667\u2010y"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c17537"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c13003"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.76540"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010024\u201001619\u20102"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010025\u201001801\u20100"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic50022a027"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202100973"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202300619"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0920\u20105861(02)00323\u20101"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2006.12.005"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.8801354","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.8801354","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.8801354","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T13:00:34Z","timestamp":1791896434000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.8801354"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,10,13]]},"references-count":38,"alternative-id":["10.1002\/anie.8801354"],"URL":"https:\/\/doi.org\/10.1002\/anie.8801354","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,10,13]]},"assertion":[{"value":"2026-08-16","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-10-06","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-10-13","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e8801354"}}