{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T00:16:04Z","timestamp":1792109764475,"version":"4.4.0"},"reference-count":72,"publisher":"Wiley","issue":"22","license":[{"start":{"date-parts":[[2026,4,14]],"date-time":"2026-04-14T00:00:00Z","timestamp":1776124800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,4,14]],"date-time":"2026-04-14T00:00:00Z","timestamp":1776124800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["92461304"],"award-info":[{"award-number":["92461304"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U24A20479"],"award-info":[{"award-number":["U24A20479"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22371263"],"award-info":[{"award-number":["22371263"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,5,25]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Methane, the most stable alkane, is significantly more stable than its partial oxidation products. This renders the highly selective conversion of CH\n                    <jats:sub>4<\/jats:sub>\n                    to CH\n                    <jats:sub>3<\/jats:sub>\n                    OH an extremely intractable challenge, especially when using molecular oxygen as the oxidant. In this work, we synthesized a bimetallic\u2010modified zeolite composite catalyst (PdCo bimetallic nanoclusters supported on H\u2010ZSM\u20105 molecular sieve, denoted as PdCo@H\u2010ZSM\u20105) via a simple impregnation method. PdCo@H\u2010ZSM\u20105 can efficiently activate H\n                    <jats:sub>2<\/jats:sub>\n                    and O\n                    <jats:sub>2<\/jats:sub>\n                    to highly selectively oxidize CH\n                    <jats:sub>4<\/jats:sub>\n                    to CH\n                    <jats:sub>3<\/jats:sub>\n                    OH under mild conditions (70\u00b0C), achieving a remarkable CH\n                    <jats:sub>3<\/jats:sub>\n                    OH yield of 2349\u00a0\u00b5mol g\n                    <jats:sub>cat<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    (249\u00a0mmol g\n                    <jats:sub>Pd<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). Significantly, PdCo@H\u2010ZSM\u20105 is the sole catalyst reported to date that can achieve over 99% CH\n                    <jats:sub>3<\/jats:sub>\n                    OH selectivity in the oxidation of CH\n                    <jats:sub>4<\/jats:sub>\n                    by molecular oxygen under mild conditions. This work is expected to inspire new technologies for industrial CH\n                    <jats:sub>4<\/jats:sub>\n                    to CH\n                    <jats:sub>3<\/jats:sub>\n                    OH conversion, promoting more sustainable chemistry and engineering. Furthermore, the low\u2010energy consumption, high\u2010efficiency activated oxygen catalyst eliminates the necessity for transporting and storing highly concentrated hydrogen peroxide, serving as a foundation for other green oxidation reactions.\n                  <\/jats:p>","DOI":"10.1002\/anie.8873024","type":"journal-article","created":{"date-parts":[[2026,4,14]],"date-time":"2026-04-14T07:54:26Z","timestamp":1776153266000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Highly Selective Methane\u2010to\u2010Methanol Conversion Enabled by Bimetallic Nanoclusters Using Molecular Oxygen"],"prefix":"10.1002","volume":"65","author":[{"given":"Yu","family":"Wang","sequence":"first","affiliation":[{"name":"Henan Key Laboratory of Crystalline Molecular Functional Materials Key Laboratory of Special Functional Molecular Materials (Zhengzhou University) Ministry of Education College of Chemistry Zhengzhou University  Zhengzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia\u2010Chao","family":"Liu","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Crystalline Molecular Functional Materials Key Laboratory of Special Functional Molecular Materials (Zhengzhou University) Ministry of Education College of Chemistry Zhengzhou University  Zhengzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tong","family":"Shi","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Crystalline Molecular Functional Materials Key Laboratory of Special Functional Molecular Materials (Zhengzhou University) Ministry of Education College of Chemistry Zhengzhou University  Zhengzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ren\u2010Wu","family":"Huang","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Crystalline Molecular Functional Materials Key Laboratory of Special Functional Molecular Materials (Zhengzhou University) Ministry of Education College of Chemistry Zhengzhou University  Zhengzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1134-0855","authenticated-orcid":false,"given":"Rui","family":"Wang","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Crystalline Molecular Functional Materials Key Laboratory of Special Functional Molecular Materials (Zhengzhou University) Ministry of Education College of Chemistry Zhengzhou University  Zhengzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiangyu","family":"Wang","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Crystalline Molecular Functional Materials Key Laboratory of Special Functional Molecular Materials (Zhengzhou University) Ministry of Education College of Chemistry Zhengzhou University  Zhengzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7108-5943","authenticated-orcid":false,"given":"Huijuan","family":"Wei","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Crystalline Molecular Functional Materials Key Laboratory of Special Functional Molecular Materials (Zhengzhou University) Ministry of Education College of Chemistry Zhengzhou University  Zhengzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4423-9844","authenticated-orcid":false,"given":"Zhao\u2010Yang","family":"Wang","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Crystalline Molecular Functional Materials Key Laboratory of Special Functional Molecular Materials (Zhengzhou University) Ministry of Education College of Chemistry Zhengzhou University  Zhengzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6728-0559","authenticated-orcid":false,"given":"Shuang\u2010Quan","family":"Zang","sequence":"additional","affiliation":[{"name":"Henan Key Laboratory of Crystalline Molecular Functional Materials Key Laboratory of Special Functional Molecular Materials (Zhengzhou University) Ministry of Education College of Chemistry Zhengzhou University  Zhengzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,4,14]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.344.6191.1464"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c04374"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00715"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201410738"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010019\u20100273\u2010z"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202302143"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010020\u201014742\u2010x"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b11010"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202013807"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1872\u20102067(23)64485\u20107"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.022.202201991"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2016.06.020"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.1c00129"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201044839\u20106"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202205077"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201054101\u20108"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010023\u201001011\u20105"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11244\u2010020\u201001247\u20106"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201024912\u20100"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c03985"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201604708"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2020.119827"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c00905"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200703928"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010021\u201000725\u20108"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201908909"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c04675"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b04906"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar1001473"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201207717"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c04260"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202201540"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2022.121223"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaw1108"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2019.02.043"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202204116"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtnano.2024.100506"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202201630"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2020.117711"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c02823"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.2c02031"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1NJ01283E"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201812827"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7TA00710H"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2025.02.120"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010022\u201032450\u20106"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010022\u201033757\u20100"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c00656"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b02871"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE03508A"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c02121"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b00714"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c09141"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b11440"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c11683"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202420606"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c05103"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201812184"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c05910"},{"key":"e_1_2_7_61_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE02671C"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.9b01992"},{"key":"e_1_2_7_63_1","doi-asserted-by":"publisher","DOI":"10.1002\/agt2.70046"},{"key":"e_1_2_7_64_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1872\u20102067(22)64191\u20103"},{"key":"e_1_2_7_65_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2023.108418"},{"key":"e_1_2_7_66_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c09665"},{"key":"e_1_2_7_67_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201064505\u20109"},{"key":"e_1_2_7_68_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274\u2010023\u20106152\u20106"},{"key":"e_1_2_7_69_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.0c04329"},{"key":"e_1_2_7_70_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c07179"},{"key":"e_1_2_7_71_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c10369"},{"key":"e_1_2_7_72_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abd5803"},{"key":"e_1_2_7_73_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1872\u20105813(23)60412\u20108"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.8873024","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.8873024","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.8873024","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,6,12]],"date-time":"2026-06-12T19:19:40Z","timestamp":1781291980000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.8873024"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,4,14]]},"references-count":72,"journal-issue":{"issue":"22","published-print":{"date-parts":[[2026,5,25]]}},"alternative-id":["10.1002\/anie.8873024"],"URL":"https:\/\/doi.org\/10.1002\/anie.8873024","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,4,14]]},"assertion":[{"value":"2026-02-27","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-04-06","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-04-14","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e8873024"}}