{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,19]],"date-time":"2026-09-19T16:07:38Z","timestamp":1789834058388,"version":"4.0.1"},"reference-count":45,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,19]],"date-time":"2026-09-19T00:00:00Z","timestamp":1789776000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,19]],"date-time":"2026-09-19T00:00:00Z","timestamp":1789776000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["22120240388"],"award-info":[{"award-number":["22120240388"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Sulfur redox in lithium\u2013sulfur (Li\u2013S) batteries is governed by a multistep liquid\u2013solid conversion network involving soluble polysulfide intermediates and continuously evolving solid\u2013liquid interfaces. Here we identify an electrochemically self\u2010driven interfacial anion\u2010transfer process at a CoPSe\u2010based catalytic interface that reshapes sulfur redox pathway. During discharge, selenium released from the catalyst surface becomes incorporated into sulfur intermediates, redirecting sulfur reduction toward Se\u2010containing species that facilitate bond cleavage, favor shorter\u2010chain intermediates, and accelerate Li\n                    <jats:sub>2<\/jats:sub>\n                    S formation. Meanwhile, partial selenium extraction generates Se\u2010deficient catalytic sites with enhanced polysulfide affinity, promoting intermediate anchoring and liquid\u2010to\u2010solid conversion. Through this coupled evolution of sulfur species and catalytic sites, the interface operates in an operando adaptive mode rather than merely accelerating conventional polysulfide conversion. The resulting Li\u2013S cells deliver 703 mAh g\u2013\n                    <jats:sup>1<\/jats:sup>\n                    at 5 C with a capacity decay of 0.016% per cycle over 1,000 cycles at 2 C. This work establishes interfacial anion transfer as a route to pathway\u2010level sulfur\u2010redox regulation and adaptive catalyst evolution as a design principle for multistep electrochemical reactions.\n                  <\/jats:p>","DOI":"10.1002\/anie.9043892","type":"journal-article","created":{"date-parts":[[2026,9,19]],"date-time":"2026-09-19T15:59:21Z","timestamp":1789833561000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Electrochemically Self\u2010Driven Interfacial Selenium Transfer Reshapes Sulfur Redox Pathway in Lithium\u2013Sulfur Batteries"],"prefix":"10.1002","author":[{"given":"Yutong","family":"Feng","sequence":"first","affiliation":[{"name":"School of Chemical Science and Engineering State Key Laboratory of Cardiovascular Diseases Shanghai East Hospital Tongji University  Shanghai P. R. China"},{"name":"College of Energy Materials and Chemistry College of Chemistry and Chemical Engineering Inner Mongolia University Hohhot P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cunyi","family":"Peng","sequence":"additional","affiliation":[{"name":"School of Chemical Science and Engineering State Key Laboratory of Cardiovascular Diseases Shanghai East Hospital Tongji University  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shufen","family":"Tan","sequence":"additional","affiliation":[{"name":"School of Chemical Science and Engineering State Key Laboratory of Cardiovascular Diseases Shanghai East Hospital Tongji University  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian","family":"Ma","sequence":"additional","affiliation":[{"name":"School of Chemical Science and Engineering State Key Laboratory of Cardiovascular Diseases Shanghai East Hospital Tongji University  Shanghai P. R. China"},{"name":"College of Materials and Chemical Engineering Fuyang University of Technology  Anhui P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5991-0955","authenticated-orcid":false,"given":"Xiaoning","family":"Li","sequence":"additional","affiliation":[{"name":"Centre For Atomaterials and Nanomanufacturing (CAN) School of Science RMIT University  Melbourne VIC Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tongtong","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemical Science and Engineering State Key Laboratory of Cardiovascular Diseases Shanghai East Hospital Tongji University  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lu","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemical Science and Engineering State Key Laboratory of Cardiovascular Diseases Shanghai East Hospital Tongji University  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Xu","sequence":"additional","affiliation":[{"name":"Department of Optometry, Shanghai Eye Diseases Prevention &amp; Treatment Center\/Shanghai Eye Hospital, School of Medicine, Tongji University National Clinical Research Center for Eye Diseases; Shanghai Engineering Research Center of Precise Diagnosis and Treatment of Eye Diseases  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruijin","family":"Meng","sequence":"additional","affiliation":[{"name":"School of Chemical Science and Engineering State Key Laboratory of Cardiovascular Diseases Shanghai East Hospital Tongji University  Shanghai P. R. 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