{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T03:59:33Z","timestamp":1790827173494,"version":"4.1.0"},"reference-count":47,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T00:00:00Z","timestamp":1790726400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T00:00:00Z","timestamp":1790726400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52433002"],"award-info":[{"award-number":["52433002"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52503108"],"award-info":[{"award-number":["52503108"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The formation and decomposition of Li\n                    <jats:sub>2<\/jats:sub>\n                    CO\n                    <jats:sub>3<\/jats:sub>\n                    dictate the reversibility of Li\u2010CO\n                    <jats:sub>2<\/jats:sub>\n                    batteries. However, as an electronically insulating and stable solid, the random deposition of Li\n                    <jats:sub>2<\/jats:sub>\n                    CO\n                    <jats:sub>3<\/jats:sub>\n                    causes interfacial blockage and high decomposition barriers, severely limiting performance. Herein, we propose a facet\u2010preferred growth strategy to regulate the structure of discharge products. Different Li\n                    <jats:sub>2<\/jats:sub>\n                    CO\n                    <jats:sub>3<\/jats:sub>\n                    facets possess distinct surface energies, atomic arrangements, and interfacial reactivities, making selective growth an effective route to optimize electrochemical behavior. This process is governed by catalyst\u2010product interfacial interactions, requiring both structural adaptability and tunable electronic coupling. Layered MoS\n                    <jats:sub>2<\/jats:sub>\n                    is selected as a model catalyst due to its two\u2010dimensional structure and phase\u2010dependent electronic properties. By constructing a MoS\n                    <jats:sub>2<\/jats:sub>\n                    @CuS heterointerface, a controllable 2H to 1T phase transition is induced, reconstructing the interfacial electronic structure and directing the oriented growth of Li\n                    <jats:sub>2<\/jats:sub>\n                    CO\n                    <jats:sub>3<\/jats:sub>\n                    . Consequently, the battery exhibits a low overpotential (0.46\u00a0V), high energy efficiency (\u223c92.4%), and excellent cycling stability (&gt;1800\u00a0h). Theoretical calculations reveal that 1T\u2010MoS\n                    <jats:sub>2<\/jats:sub>\n                    exhibits stronger interfacial interactions with Li\n                    <jats:sub>2<\/jats:sub>\n                    CO\n                    <jats:sub>3<\/jats:sub>\n                    , preferentially stabilizing the (\u2010110) facet, lowering decomposition barriers, and promoting oriented nucleation and epitaxial growth. This work establishess a direct link among catalyst structure, interfacial interaction, and product crystallographic orientation, providing a new strategy for high\u2010performance Li\u2010CO\n                    <jats:sub>2<\/jats:sub>\n                    batteries.\n                  <\/jats:p>","DOI":"10.1002\/anie.9049103","type":"journal-article","created":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T03:49:41Z","timestamp":1790826581000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Interfacial Phase Transformation Enabled Crystallographic Selectivity for Efficient Li\n                    <sub>2<\/sub>\n                    CO\n                    <sub>3<\/sub>\n                    Decomposition Toward Long\u2010Cycling Li\u2010CO\n                    <sub>2<\/sub>\n                    Batteries"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0000-9009-7296","authenticated-orcid":false,"given":"Jiyuan","family":"Xiao","sequence":"first","affiliation":[{"name":"School of Chemistry, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, \u201cFour Joint Subjects One Union\u201d School\u2010Enterprise Joint Research Center for Power Battery Recycling &amp; Circulation Utilization Technology Xi'an Jiaotong University  Xi'an P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lijun","family":"Feng","sequence":"additional","affiliation":[{"name":"School of Chemistry, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, \u201cFour Joint Subjects One Union\u201d School\u2010Enterprise Joint Research Center for Power Battery Recycling &amp; Circulation Utilization Technology Xi'an Jiaotong University  Xi'an P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoran","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemistry, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, \u201cFour Joint Subjects One Union\u201d School\u2010Enterprise Joint Research Center for Power Battery Recycling &amp; Circulation Utilization Technology Xi'an Jiaotong University  Xi'an P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-7848-895X","authenticated-orcid":false,"given":"Yanyang","family":"Qin","sequence":"additional","affiliation":[{"name":"School of Physics Xidian University  Xi'an P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiatian","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemistry, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, \u201cFour Joint Subjects One Union\u201d School\u2010Enterprise Joint Research Center for Power Battery Recycling &amp; Circulation Utilization Technology Xi'an Jiaotong University  Xi'an P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sen","family":"Dang","sequence":"additional","affiliation":[{"name":"School of Chemistry, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, \u201cFour Joint Subjects One Union\u201d School\u2010Enterprise Joint Research Center for Power Battery Recycling &amp; Circulation Utilization Technology Xi'an Jiaotong University  Xi'an P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Menghang","family":"Sun","sequence":"additional","affiliation":[{"name":"School of Chemistry, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, \u201cFour Joint Subjects One Union\u201d School\u2010Enterprise Joint Research Center for Power Battery Recycling &amp; Circulation Utilization Technology Xi'an Jiaotong University  Xi'an P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Song","family":"Xue","sequence":"additional","affiliation":[{"name":"School of Chemistry, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, \u201cFour Joint Subjects One Union\u201d School\u2010Enterprise Joint Research Center for Power Battery Recycling &amp; Circulation Utilization Technology Xi'an Jiaotong University  Xi'an P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaofeng","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, \u201cFour Joint Subjects One Union\u201d School\u2010Enterprise Joint Research Center for Power Battery Recycling &amp; Circulation Utilization Technology Xi'an Jiaotong University  Xi'an P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Limin","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, \u201cFour Joint Subjects One Union\u201d School\u2010Enterprise Joint Research Center for Power Battery Recycling &amp; Circulation Utilization Technology Xi'an Jiaotong University  Xi'an P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5683-0973","authenticated-orcid":false,"given":"Shujiang","family":"Ding","sequence":"additional","affiliation":[{"name":"School of Chemistry, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, \u201cFour Joint Subjects One Union\u201d School\u2010Enterprise Joint Research Center for Power Battery Recycling &amp; Circulation Utilization Technology Xi'an Jiaotong University  Xi'an P.R. 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