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Here, we report a \u201cquadruple\u2010hydrogen\u2010bonds end\u2010capping\u201d strategy to realize high\u2010performance stretchable and healable semiconducting polymers. By incorporating quadruple hydrogen\u2010bonds between end\u2010capping units linked with alkyl spacers into polymer backbone, we engineer a supramolecular architecture that achieves enhanced crystallinity and improved ordered packing with reduced \u03c0\u2010\u03c0 stacking distance, and also superior stretchabillity with molecular\u2010ordering retention during stretching. Moreover, enhanced chain mobility together with dynamic and reversible and hydrogen\u2010bonding sites in the architecture contribute to efficient healing. Consequently, our designed semiconducting polymer exhibits a more than 2\u2010fold increase in mobility, while demonstrating stable mobility retention under strain, high mobility recovery after healing, and scalability in fully stretchable transistor arrays. This work provides an effective molecular design strategy for achieving simultaneous improvements in electrical performance, mechanical stretchability, and healing ability in organic electronics.<\/jats:p>","DOI":"10.1002\/anie.9060680","type":"journal-article","created":{"date-parts":[[2026,6,16]],"date-time":"2026-06-16T07:15:51Z","timestamp":1781594151000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Quadruple Hydrogen\u2010Bonds Engineering for Intrinsically Stretchable and Healable Semiconducting Polymers"],"prefix":"10.1002","volume":"65","author":[{"ORCID":"https:\/\/orcid.org\/0009-0005-6265-0011","authenticated-orcid":false,"given":"Yuanhe","family":"Gu","sequence":"first","affiliation":[{"name":"Laboratory of Molecular Materials and Devices College of Smart Materials and Future Energy Fudan University  Shanghai P.R. 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