{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T14:07:44Z","timestamp":1788790064467,"version":"build-2803163510"},"reference-count":47,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T00:00:00Z","timestamp":1788739200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T00:00:00Z","timestamp":1788739200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2024YFA1509500"],"award-info":[{"award-number":["2024YFA1509500"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22372004"],"award-info":[{"award-number":["22372004"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Electrochemical C\u2500N coupling from carbon dioxide and nitrogen oxoanions offers a sustainable route to value\u2010added amides, yet achieving high selectivity remains challenging due to competing reaction pathways and insufficient substrate activation. Here we report a homo\/heterogeneous dual\u2010active\u2010center catalyst that integrates molecular copper phthalocyanine with atomically dispersed chromium sites on porous carbon nanospheres to enable selective electrosynthesis of formamide under neutral conditions. The molecular Cu centers selectively reduce CO\n                    <jats:sub>2<\/jats:sub>\n                    to CO, while Cr single atoms promote nitrate (NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) and nitrite (NO\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) activation to *NO intermediates, furnishing spatially separated yet kinetically matched reactive species. As a result, the catalyst achieves a formamide faradaic efficiency (FE) of 35.2% from CO\n                    <jats:sub>2<\/jats:sub>\n                    and NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2013<\/jats:sup>\n                    , increasing to 44.9% using NO\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    , with high stability and activity even at low NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    concentrations. In situ spectroscopy and density functional theory calculations reveal *NO\u2500CO coupling via a *NOCO intermediate as the key pathway. This work establishes a general strategy for designing dual\u2010site electrocatalysts for selective C\u2500N bond formation.\n                  <\/jats:p>","DOI":"10.1002\/anie.9113894","type":"journal-article","created":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T13:10:39Z","timestamp":1788786639000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Homo\/Heterogeneous Dual Active Centers Enable Selective Electrochemical C\u2500N Coupling of CO\n                    <sub>2<\/sub>\n                    and Nitrate to Formamide"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0009-7242-4439","authenticated-orcid":false,"given":"Cheng","family":"Peng","sequence":"first","affiliation":[{"name":"College of Chemistry and Molecular Engineering Peking University  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yifan","family":"Bu","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Engineering Peking University  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shiyun","family":"Li","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Engineering Peking University  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinyi","family":"Han","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Beijing Institute of Technology  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7957-9101","authenticated-orcid":false,"given":"Chuhao","family":"Liu","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Engineering Peking University  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiuling","family":"Jiang","sequence":"additional","affiliation":[{"name":"Advanced Institute for Materials Research (WPI\u2010AIMR) Tohoku University  Sendai Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-8376-0055","authenticated-orcid":false,"given":"Yuhang","family":"Wang","sequence":"additional","affiliation":[{"name":"Advanced Institute for Materials Research (WPI\u2010AIMR) Tohoku University  Sendai Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0450-2406","authenticated-orcid":false,"given":"Yizhou","family":"Zhang","sequence":"additional","affiliation":[{"name":"Advanced Institute for Materials Research (WPI\u2010AIMR) Tohoku University  Sendai Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yifan","family":"Fu","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Engineering Peking University  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0001-4881-3428","authenticated-orcid":false,"given":"Jisheng","family":"Xie","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Engineering Peking University  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-8069-0356","authenticated-orcid":false,"given":"Jihan","family":"Zhou","sequence":"additional","affiliation":[{"name":"College of Chemistry and Molecular Engineering Peking University  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7577-1366","authenticated-orcid":false,"given":"Hao","family":"Li","sequence":"additional","affiliation":[{"name":"Advanced Institute for Materials Research (WPI\u2010AIMR) Tohoku University  Sendai Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7023-4852","authenticated-orcid":false,"given":"Konglin","family":"Wu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Metallurgical Emission Reduction &amp; Resources Recycling of Ministry of Education, School of Chemistry and Chemical Engineering Anhui University of Technology  Maanshan P. R. 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