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Here, we propose a solvation hierarchy strategy for sodium\u2013sulfur batteries to reconcile the intrinsic trade\u2010off between polysulfide confinement and reaction kinetics. The solvation hierarchy strategy includes the strong solvating, moderate solvating and weak solvating electrolyte, which establishes a tailored solvation environment that sterically excludes polysulfides to mitigate shuttling, while concurrently inducing a metastable state that lowers the desolvation energy barrier, promoting rapid charge transfer. The moderate solvating sec\u2010butyl ether (SBE) distinguished by its symmetric \u03b1\u2010methyl steric hindrance is chosen, compared to the highly solvating 1,2\u2010dimethoxyethane (DME) and the weakly solvating ethyl butyl ether (BEE). The designed solvation\u2010hierarchy electrolyte breaks the trade off in kinetic and stability, enabling a capacity decay rate of 0.015% per cycle after 800 cycles at 1C. Furthermore, the system demonstrates robust stability at practical conditions of high sulfur loadings of 6.8\u00a0mg cm\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>2<\/jats:sup>\n                    and lean electrolyte of 5.1\u00a0\u00b5L mg\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>1<\/jats:sup>\n                    and is also validated in pouch cell configurations. These findings highlight the efficacy of solvating hierarchy to balance the stability and kinetic dilemma, offering a valuable perspective for advancing high\u2010energy\u2010density metal\u2010sulfur batteries.\n                  <\/jats:p>","DOI":"10.1002\/anie.9167252","type":"journal-article","created":{"date-parts":[[2026,8,20]],"date-time":"2026-08-20T12:38:23Z","timestamp":1787229503000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Solvation\u2010Hierarchy Electrolyte for Balancing Kinetics and Stability in Sodium\u2013Sulfur Batteries"],"prefix":"10.1002","volume":"65","author":[{"given":"Ao","family":"Zhong","sequence":"first","affiliation":[{"name":"Department of Chemical Engineering, School of Environmental and Chemical Engineering Shanghai University  Shanghai 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