{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T12:04:20Z","timestamp":1790251460904,"version":"4.1.0"},"reference-count":28,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T00:00:00Z","timestamp":1790208000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T00:00:00Z","timestamp":1790208000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100014871","name":"State Key Laboratory of Advanced Chemical Power Sources","doi-asserted-by":"publisher","award":["A342\u2010JS\u20102025\u20100029"],"award-info":[{"award-number":["A342\u2010JS\u20102025\u20100029"]}],"id":[{"id":"10.13039\/501100014871","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Precise synthesis of multi\u2010component layered oxides via conventional solid\u2010state routes remains a fundamental challenge, often constrained by the disparate reaction windows and mass transport kinetics of heterogeneous precursors. In this study, leveraging the close topological relationship between spinel and layered oxides that share close\u2010packed oxygen frameworks, we develop a spinel\u2010templated solid\u2010state strategy to redirect phase\u2010evolution pathways. By integrating in situ x\u2010ray diffraction with density functional theory calculations, we reveal distinct lithiation and sodiation pathways across mono\u2010 and multi\u2010component spinel systems. Crucially, the anti\u2010site defect formation energy (\n                    <jats:italic>E<\/jats:italic>\n                    <jats:sub>as<\/jats:sub>\n                    ) serves as the key energetic descriptor that captures the accessibility of cation\u2010mixed intermediate configurations, thereby accounting for this pathway divergence. Relative to traditional multi\u2010precursor routes, the spinel\u2010based strategy promotes a more integrated reaction pathway, improving elemental homogeneity and suppressing impurity formation in layered cathodes. These findings highlight how precursor topology and defect\u2010related energetics can be coupled to steer phase evolution in solid\u2010state reactions, offering a design perspective for compositionally complex oxides and related functional materials.\n                  <\/jats:p>","DOI":"10.1002\/anie.9169593","type":"journal-article","created":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T11:08:49Z","timestamp":1790248129000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Spinel\u2010Based Solid\u2010State Reactions: From Spinel Oxides to Lithium or Sodium Layered Oxides"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2021-1780","authenticated-orcid":false,"given":"Yuqi","family":"Zhou","sequence":"first","affiliation":[{"name":"Institute of New Energy and Low\u2010Carbon Technology (INELT) Sichuan University  Chengdu Sichuan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ting","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute of New Energy and Low\u2010Carbon Technology (INELT) Sichuan University  Chengdu Sichuan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yulin","family":"Xu","sequence":"additional","affiliation":[{"name":"Institute of New Energy and Low\u2010Carbon Technology (INELT) Sichuan University  Chengdu Sichuan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinglin","family":"Tang","sequence":"additional","affiliation":[{"name":"Institute of New Energy and Low\u2010Carbon Technology (INELT) Sichuan University  Chengdu Sichuan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fangzhou","family":"Zhao","sequence":"additional","affiliation":[{"name":"Institute of New Energy and Low\u2010Carbon Technology (INELT) Sichuan University  Chengdu Sichuan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ye","family":"Tao","sequence":"additional","affiliation":[{"name":"Institute of New Energy and Low\u2010Carbon Technology (INELT) Sichuan University  Chengdu Sichuan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peng","family":"Liu","sequence":"additional","affiliation":[{"name":"Institute of New Energy and Low\u2010Carbon Technology (INELT) Sichuan University  Chengdu Sichuan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wanglai","family":"Cen","sequence":"additional","affiliation":[{"name":"Institute of New Energy and Low\u2010Carbon Technology (INELT) Sichuan University  Chengdu Sichuan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianyong","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Chemical Power Sources Guizhou Meiling Power Sources Co. Ltd.  Zunyi Guizhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4963-2936","authenticated-orcid":false,"given":"Yongzhi","family":"Zhang","sequence":"additional","affiliation":[{"name":"Institute of New Energy and Low\u2010Carbon Technology (INELT) Sichuan University  Chengdu Sichuan China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,24]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja3091438"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3ee40847g"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/d0ee01277g"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010025\u201001963\u2010x"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.5c03519"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202300378"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202505824"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c12098"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adx3927"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160\u2010024\u201000502\u2010y"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c15943"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202312292"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202518277"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2014.07.178"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.0c02568"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2020.228422"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.9b05279"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.2c02050"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adp3309"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202408642"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202420706"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1080\/01411594.2010.541856"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.035112jes"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0567739476001551"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202503660"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c11049"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5c02960"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.5c02679"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.9169593","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.9169593","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.9169593","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T11:08:50Z","timestamp":1790248130000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.9169593"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,24]]},"references-count":28,"alternative-id":["10.1002\/anie.9169593"],"URL":"https:\/\/doi.org\/10.1002\/anie.9169593","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,24]]},"assertion":[{"value":"2026-06-18","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-17","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-24","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e9169593"}}