{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,24]],"date-time":"2026-10-24T20:28:09Z","timestamp":1792873689993,"version":"4.5.0"},"reference-count":60,"publisher":"Wiley","issue":"37","license":[{"start":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T00:00:00Z","timestamp":1783382400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T00:00:00Z","timestamp":1783382400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52303144"],"award-info":[{"award-number":["52303144"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100010211","name":"Education Department of Jilin Province","doi-asserted-by":"publisher","award":["JJKH20250696KJ"],"award-info":[{"award-number":["JJKH20250696KJ"]}],"id":[{"id":"10.13039\/501100010211","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,9,7]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Hydrogel electrolytes are promising candidates for zinc\u2010based energy storage systems (ZESs) owing to their superior safety features, favorable ionic conductivity and interfacial compatibility. However, current hydrogel electrolytes suffer from weak mechanical strength, low Zn\n                    <jats:sup>2+<\/jats:sup>\n                    transference numbers, causing Zn dendrite growth and parasitic reactions, while the common permanent covalent crosslinked polymer matrices are non\u2010recyclable. Herein, a supramolecular hydrogel electrolyte that achieves robust mechanical rigidity with high Zn\n                    <jats:sup>2+<\/jats:sup>\n                    mobility is developed by introducing guanylate quadruplex (G\u2010quadruplex), which effectively regulates concentration gradients and confines water activity. Experimental characterizations and theoretical simulations display that the G\u2010quadruplex polyanionic network restrains water activity, homogenizes Zn\n                    <jats:sup>2+<\/jats:sup>\n                    flux and uniforms electric field, effectively stabilize the Zn anode. The hydrogel electrolyte enables durable cycling life of 3,800 hours at 1\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and 1,800 hours at 10\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    in Zn\/\/Zn symmetric cells. Additionally, the zinc\u2010ion hybrid supercapacitors display outstanding electrochemical performance and high safety, achieving 97.4% capacity retention over 10\u00a0000 cycles. Moreover, the wasted supramolecular hydrogel can be facilely depolymerized back into monomers and biomacromolecules with negligible performances loss, underscoring its recyclability advantage over conventional covalently crosslinked hydrogels. This work provides a supramolecular engineering strategy that overcomes the trade\u2010offs in hydrogel electrolytes, advancing sustainable and durable ZESs.\n                  <\/jats:p>","DOI":"10.1002\/anie.9230301","type":"journal-article","created":{"date-parts":[[2026,7,7]],"date-time":"2026-07-07T18:40:42Z","timestamp":1783449642000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Closed\u2010loop Recyclable and Robust Supramolecular Hydrogel Electrolytes With High Zinc Ion Mobility for Stable Zinc Anode"],"prefix":"10.1002","volume":"65","author":[{"given":"Xuming","family":"Liu","sequence":"first","affiliation":[{"name":"Polymeric and Soft Materials Laboratory School of Chemistry and Life Science and Advanced Institute of Materials Science Changchun University of Technology  Changchun China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yingang","family":"Ma","sequence":"additional","affiliation":[{"name":"Polymeric and Soft Materials Laboratory School of Chemistry and Life Science and Advanced Institute of Materials Science Changchun University of Technology  Changchun China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuang","family":"Chen","sequence":"additional","affiliation":[{"name":"Polymeric and Soft Materials Laboratory School of Chemistry and Life Science and Advanced Institute of Materials Science Changchun University of Technology  Changchun China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8219-9727","authenticated-orcid":false,"given":"Xin","family":"Liu","sequence":"additional","affiliation":[{"name":"Polymeric and Soft Materials Laboratory School of Chemical Engineering and Advanced Institute of Materials Science Changchun University of Technology  Changchun China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-9185-6286","authenticated-orcid":false,"given":"Qin","family":"Zhang","sequence":"additional","affiliation":[{"name":"Polymeric and Soft Materials Laboratory School of Chemistry and Life Science and Advanced Institute of Materials Science Changchun University of Technology  Changchun China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,7]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010025\u201009266\u20107"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201040337\u20103"},{"key":"e_1_2_7_4_1","article-title":"Schottky Barrier Engineering via Coordination Chemistry: A Pathway Toward Advanced Photocatalytic Remediation of Volatile Organic Compounds","volume":"549","author":"Yuan F.","year":"2026","journal-title":"Coordination Chemistry Reviews"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201048368\u20100"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201039947\u20108"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/sus2.184"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202300608"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202507403"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893\u2010023\u201001092\u2010x"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1EE03377H"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893\u2010025\u201001646\u20101"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE05442C"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5EE04572J"},{"key":"e_1_2_7_15_1","article-title":"Simultaneously Constructing Anion Barrier and Fast Zn2\n                  + Conduction Channels via Heterostructured Solid Electrolyte Interphase for Zinc Metal Batteries","volume":"35","author":"Dong Y.","year":"2025","journal-title":"Advanced Functional Materials"},{"key":"e_1_2_7_16_1","article-title":"Cascade Effect of Bioinspired Slow\u2010release Protective Layer on Zinc Anode Toward Stable Aqueous Zinc\u2010metal Batteries","volume":"78","author":"Fu K.","year":"2025","journal-title":"Energy Storage Materials"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202423118"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202300019"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010022\u201035215\u20103"},{"key":"e_1_2_7_20_1","first-page":"9","article-title":"In Situ Constructing an Elastic Polymer Interphase Layer via Cation Condensation Chemistry for Dendrite\u2010Free Aqueous Zinc Metal Batteries","volume":"64","author":"Wang Y. 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