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However, the attractive mild\u2010temperature operating window imposes kinetic constraints on C\u2500H\/C\u2550O activation and promotes thermodynamic tendencies for coke formation, resulting in limited efficiency and stability. Herein, manganese oxide (MnO\n                    <jats:sub>x<\/jats:sub>\n                    ) is employed as a multifunctional support to integrate the classic Rh catalytic center, establishing a new benchmark photothermo catalyst for DRM. The system achieves record\u2010high syngas production rates (H\n                    <jats:sub>2<\/jats:sub>\n                    : 948\u00a0mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    ; CO: 992\u00a0mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) without external heating, alongside exceptional long\u2010term stability (\u223c500\u00a0h). These production rates and stability also surpass conventional thermocatalysts in similar temperature ranges, with stability exceeding most thermocatalysts by an order of magnitude. Under a separate low\u2010conversion, high\u2010gas hourly space velocity (GHSV) protocol, a light\u2010to\u2010chemical efficiency (29.5%) can also be reached. MnO\n                    <jats:sub>x<\/jats:sub>\n                    functions as a broadband light harvester, generating a localized thermal field at the micrometre\u2010scale via an efficient photon\u2010to\u2010phonon pathway to facilitate C\u2500H bond activation on Rh. Concurrently, its active lattice oxygen enables a dynamic O\n                    <jats:sub>L<\/jats:sub>\n                    \u2010O\n                    <jats:sub>V<\/jats:sub>\n                    cycle for timely removal of C* intermediates and C\u2550O activation. This work underscores the critical role of support engineering in advancing light\u2010driven DRM.\n                  <\/jats:p>","DOI":"10.1002\/anie.9236832","type":"journal-article","created":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T14:25:31Z","timestamp":1785939931000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synergy Between Photon\u2010to\u2010Phonon Pathway and Active Lattice Oxygen Enables Efficient and Stable Syngas Synthesis"],"prefix":"10.1002","volume":"65","author":[{"ORCID":"https:\/\/orcid.org\/0009-0007-0380-1099","authenticated-orcid":false,"given":"Chengzhi","family":"Guo","sequence":"first","affiliation":[{"name":"Department of Chemical Engineering University College London  London 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