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Inspired by these biological systems, synthetic model complexes have been developed that exploit bimetallic cooperativity to achieve analogous reactivity. In this work, we report a bimetallic Ni\u2212Zn complex comprising a pincer\u2010type diamido\u2010diaminodiphosphine ligand, in which a weakly Lewis acidic Zn(II) center stabilizes a T\u2010shaped Ni(0) site. Subsequent reactivity with H\n                    <jats:sub>2<\/jats:sub>\n                    led to the isolation of a rare Ni dihydride complex, which dynamically interconverts between Zn(\n                    <jats:italic>\u03bc<\/jats:italic>\n                    \u2010H)Ni(H) and\n                    <jats:italic>trans<\/jats:italic>\n                    \u2010Ni(H)\n                    <jats:sub>2<\/jats:sub>\n                    motifs via rotational rocking about the P\u2212Ni\u2212P axis. The Ni dihydride complex is a competent alkene hydrogenation catalyst (5 mol% loading, 70\u00b0C, 2\u00a0bar H\n                    <jats:sub>2<\/jats:sub>\n                    ) for terminal olefins. Also, the Ni dihydride inserts CO\n                    <jats:sub>2<\/jats:sub>\n                    to give a rare Ni hydrido formate. This product further reacts with a second equivalent of CO\n                    <jats:sub>2<\/jats:sub>\n                    through a carboxylate shift mechanism that unveils a nucleophilic Zn(II) amide group that inserts CO\n                    <jats:sub>2<\/jats:sub>\n                    to give carbamate. Collectively, our experimental and computational results highlight the role of Zn(II) as a weakly Lewis acidic partner, which promotes the dual activation of H\n                    <jats:sub>2<\/jats:sub>\n                    and CO\n                    <jats:sub>2<\/jats:sub>\n                    by a single Ni center in the absence of any external base.\n                  <\/jats:p>","DOI":"10.1002\/anie.9254970","type":"journal-article","created":{"date-parts":[[2026,6,20]],"date-time":"2026-06-20T09:08:08Z","timestamp":1781946488000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Dual Activation of H\n                    <sub>2<\/sub>\n                    and CO\n                    <sub>2<\/sub>\n                    by a Pincer\u2010Type Ni\u2013Zn Heterobimetallic Complex"],"prefix":"10.1002","volume":"65","author":[{"given":"Krishnendu","family":"Dey","sequence":"first","affiliation":[{"name":"Institut 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