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This quasi\u2010two\u2010dimensional transport amplifies local electric\u2010field and concentration heterogeneities, leading to uneven nucleation and dendritic growth. Here, we demonstrate that Zn deposition can be fundamentally regulated by reprogramming the dimensionality of ion transport. A three\u2010dimensionally interpenetrated covalent organic framework (COF) incorporating crown\u2010ether moieties is embedded into a hydrogel electrolyte. The confined macrocyclic sites selectively coordinate Zn\n                    <jats:sup>2+<\/jats:sup>\n                    and partially displace solvating water molecules, while the interconnected crystalline channels enable continuous, isotropic bulk ion migration. This architecture converts Zn\n                    <jats:sup>2+<\/jats:sup>\n                    transport from interface\u2010limited diffusion to bulk\u2010governed three\u2010dimensional flux, resulting in intrinsically uniform Zn deposition. Consequently, symmetric Zn cells exhibit stable cycling for over 2000\u00a0h at 1\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , and Zn||NH\n                    <jats:sub>4<\/jats:sub>\n                    V\n                    <jats:sub>4<\/jats:sub>\n                    O\n                    <jats:sub>10<\/jats:sub>\n                    full cells retain 81.6% of their capacity after 3000 cycles. These findings identify ion\u2010transport dimensionality as a key descriptor for metal\u2010deposition stability and establish a general electrolyte\u2010engineering strategy that transcends conventional regulation.\n                  <\/jats:p>","DOI":"10.1002\/anie.9280894","type":"journal-article","created":{"date-parts":[[2026,7,10]],"date-time":"2026-07-10T09:42:34Z","timestamp":1783676554000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Reprogramming Ion\u2010Transport Dimensionality via Crystal\u2010Channel Engineering to Stabilize Zinc Anodes"],"prefix":"10.1002","volume":"65","author":[{"given":"Xiaowei","family":"Zhang","sequence":"first","affiliation":[{"name":"School of Chemistry, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, National Innovation Platform (Center) for Industry\u2010Education Integration of Energy Storage Technology, State Key Laboratory of Electrical Insulation and Power Equipment, Engineering Research Center of Energy Storage Material and Chemistry, Universities of Shaanxi Province Xi'an Jiaotong University  Xi'an Shaanxi P. R. China"},{"name":"Department Center for Advanced Materials Research Zhongyuan University of Technology  Henan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Diandian","family":"Han","sequence":"additional","affiliation":[{"name":"Department Center for Advanced Materials Research Zhongyuan University of Technology  Henan P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zekai","family":"Mei","sequence":"additional","affiliation":[{"name":"School of Instrument Science and Technology Xi'an Jiaotong University  Xi'an Shaanxi P. R. 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