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However, an equimolar amount of CO\n                    <jats:sub>2<\/jats:sub>\n                    is released during fermentation, making the process less efficient. Utilizing this released CO\n                    <jats:sub>2<\/jats:sub>\n                    directly in an electrolyzer can further reduce carbon emissions, ultimately reaching a CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010negative carbon balance. We coupled the electrochemical CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction reaction with ethanol oxidation as the anode reaction for acetate production. A nickel foam\u2010supported cobalt selenium catalyst, which is highly active for ethanol oxidation, reached a Faradaic efficiency of nearly 96% towards acetate. A high production rate of 95.2\u00a0\u00b5mol cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    min\n                    <jats:sup>\u22121<\/jats:sup>\n                    at a current density of 1 A cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    in a model flow\u2010through electrolyzer was achieved. For coupled electrolysis at 100\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , we achieved 99% and 95% FE for CO and acetate at the cathode and anode, respectively. Furthermore, using a defect\u2010Cu\u2010triazole catalyst on the gas diffusion cathode, we show a tandem cell system coupled with ethanol oxidation in both reactors for selective acetate production. This proof\u2010of\u2010concept approach can be further developed for a greener approach to bioethanol and acetate production.\n                  <\/jats:p>","DOI":"10.1002\/anie.9339732","type":"journal-article","created":{"date-parts":[[2026,4,2]],"date-time":"2026-04-02T14:15:32Z","timestamp":1775139332000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Coupling Electrochemical CO\n                    <sub>2<\/sub>\n                    Reduction With Ethanol Oxidation for Acetate Production in a Dual\u2010Electrolyzer System"],"prefix":"10.1002","volume":"65","author":[{"given":"Anirudha","family":"Shekhawat","sequence":"first","affiliation":[{"name":"Analytical Chemistry\u2010Center for Electrochemical Sciences (CES) Faculty of Chemistry and Biochemistry Ruhr University Bochum  Bochum Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shubhadeep","family":"Chandra","sequence":"additional","affiliation":[{"name":"Analytical Chemistry\u2010Center for Electrochemical Sciences (CES) Faculty of Chemistry and Biochemistry Ruhr University Bochum  Bochum Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ridha","family":"Zerdoumi","sequence":"additional","affiliation":[{"name":"Analytical Chemistry\u2010Center for Electrochemical Sciences (CES) Faculty of Chemistry and Biochemistry Ruhr University Bochum  Bochum Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bashir","family":"Eid","sequence":"additional","affiliation":[{"name":"Analytical Chemistry\u2010Center for Electrochemical Sciences (CES) Faculty of Chemistry and Biochemistry Ruhr University Bochum  Bochum Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Muhammad Adib Abdillah","family":"Mahbub","sequence":"additional","affiliation":[{"name":"Analytical Chemistry\u2010Center for Electrochemical Sciences (CES) Faculty of Chemistry and Biochemistry Ruhr University Bochum  Bochum Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2916-5223","authenticated-orcid":false,"given":"Wolfgang","family":"Schuhmann","sequence":"additional","affiliation":[{"name":"Analytical Chemistry\u2010Center for Electrochemical Sciences (CES) Faculty of Chemistry and Biochemistry Ruhr University Bochum  Bochum Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,4,2]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.esr.2024.101634"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1186\/s13068-024-02571-9"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.energyfuels.3c03758"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nexus.2023.100258"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.3c00151"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.pecs.2012.03.002"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cogsc.2020.04.005"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scca.2024.100053"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.3390\/fermentation9080709"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.3390\/beverages2040030"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.biortech.2010.01.006"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8RE00054A"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202501404"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202502846"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/celc.202500413"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274\u2010023\u20106023\u20101"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/celc.202400512"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44286\u2010024\u201000076\u20108"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.4c01995"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1088\/2515\u20107655\/acbb2a"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2022.214984"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1515\/ijmr\u20101940\u2010320801"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/0025\u20105408(67)90026\u20108"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022\u20105088(64)90108\u20100"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2010.10.051"},{"key":"e_1_2_7_27_1","volume-title":"Handbook of X\u2010ray Photoelectron Spectroscopy","author":"Moulder J. 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