{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,22]],"date-time":"2026-10-22T07:39:00Z","timestamp":1792654740488,"version":"4.5.0"},"reference-count":62,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T00:00:00Z","timestamp":1792540800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T00:00:00Z","timestamp":1792540800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22301007"],"award-info":[{"award-number":["22301007"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22475004"],"award-info":[{"award-number":["22475004"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22503001"],"award-info":[{"award-number":["22503001"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003995","name":"Natural Science Foundation of Anhui Province","doi-asserted-by":"publisher","award":["2508085QB062"],"award-info":[{"award-number":["2508085QB062"]}],"id":[{"id":"10.13039\/501100003995","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100013314","name":"Higher Education Discipline Innovation Project","doi-asserted-by":"publisher","award":["D26004"],"award-info":[{"award-number":["D26004"]}],"id":[{"id":"10.13039\/501100013314","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Developing an efficient photocatalytic system for CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction is a sustainable strategy for producing value\u2010added products. However, conversion efficiency is significantly limited by ineffective coordination among light harvesting, excited\u2010state dynamics, and interfacial electron transfer. Herein, we report a binary photocatalytic system for CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction by integrating an exfoliable Ru\u2010integrated covalent\u2013organic framework (COF\u2013Ru\u2013TPY) with a molecular cocatalyst ([M(bpy)\n                    <jats:sub>3<\/jats:sub>\n                    ]\n                    <jats:sup>2+<\/jats:sup>\n                    ). Compared with the non\u2010metalated COF, this atom\u2010level\u2010precise integration strategy not only broadens visible light absorption and narrows the optical band gap but also prolongs the excited\u2010state lifetime. Notably, the COF\u2013Ru\u2013TPY\/[Zn(bpy)\n                    <jats:sub>3<\/jats:sub>\n                    ]\n                    <jats:sup>2+<\/jats:sup>\n                    achieves a competitive CO production rate of 1.01\u00a0mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    and &gt; 99% CO selectivity, comparing favorably with representative COF\u2010based photocatalytic systems. Combined experimental characterizations and theoretical calculations indicate that precisely anchoring Ru(TPY)\n                    <jats:sub>2<\/jats:sub>\n                    chromophores improved the optical response and excited\u2010state behavior of the COF. Calculations suggested a lower work function. The Ru\u2010integrated framework provides a more polarized electronic environment that is beneficial for charge redistribution. This work highlights that atom\u2010level\u2010precise anchoring of molecular chromophores is an effective strategy for constructing COF\u2010based binary photocatalytic systems with improved excited\u2010state utilization and interfacial charge transfer.\n                  <\/jats:p>","DOI":"10.1002\/anie.9400711","type":"journal-article","created":{"date-parts":[[2026,10,22]],"date-time":"2026-10-22T06:55:41Z","timestamp":1792652141000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Atomically Precise Integration of Ruthenium\u2013Terpyridine Chromophores Into Covalent\u2013Organic Frameworks Affords Exfoliable Platforms for Synergistic Photocatalytic CO\n                    <sub>2<\/sub>\n                    Reduction"],"prefix":"10.1002","author":[{"given":"Shuai","family":"Chen","sequence":"first","affiliation":[{"name":"The Key Laboratory of Functional Molecular Solids College of Chemistry and Materials Science Anhui Normal University  Wuhu Anhui China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fan","family":"Yang","sequence":"additional","affiliation":[{"name":"The Key Laboratory of Functional Molecular Solids College of Chemistry and Materials Science Anhui Normal University  Wuhu Anhui China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1601-7574","authenticated-orcid":false,"given":"Pin","family":"Song","sequence":"additional","affiliation":[{"name":"The Key Laboratory of Functional Molecular Solids College of Chemistry and Materials Science Anhui Normal University  Wuhu Anhui China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7799-810X","authenticated-orcid":false,"given":"Yu","family":"Cui","sequence":"additional","affiliation":[{"name":"The Key Laboratory of Functional Molecular Solids College of Chemistry and Materials Science Anhui Normal University  Wuhu Anhui China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan","family":"Yue","sequence":"additional","affiliation":[{"name":"The Key Laboratory of Functional Molecular Solids College of Chemistry and Materials Science Anhui Normal University  Wuhu Anhui China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7021-8705","authenticated-orcid":false,"given":"Ning","family":"Huang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Silicon and Advanced Semiconductor Materials Department of Polymer Science and Engineering Zhejiang University  Hangzhou Zhejiang China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,21]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0603395103"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00370"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.6b02181"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b00440"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2020.213262"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2022.214440"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtchem.2023.101802"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2021.214018"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202500550"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2019.03.019"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1120411"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja8096256"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aal1585"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00550"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b09705"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b02997"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC03800K"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c06920"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c00126"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202309820"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c11146"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c04185"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202418422"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202415202"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c18450"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/0010\u20108545(82)85003\u20100"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/0010\u20108545(88)80032\u20108"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1007\/978\u20103\u2010540\u201073347\u2010810.1007\/128_2007_133"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b01920"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201701627"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202102729"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.023.202202688"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja308278w"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2CS35072F"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889881009618"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/b912468c"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b09502"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn5000223"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/pssb.19660150224"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11120\u2010009\u20109454\u2010y"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.commatsci.2005.04.010"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp047349j"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202401388"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202411315"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4TA02453B"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2019.05.033"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.1c02660"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4TA06611A"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4SC07077A"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201037545\u20102"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2021.120814"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.141360"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11426\u2010020\u20109801\u20103"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c05449"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/prechem.4c00058"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CY00176F"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.1c00862"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1872\u20102067(20)63603\u20108"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201903545"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TA07686H"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202000929"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c03897"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.9400711","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.9400711","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.9400711","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,22]],"date-time":"2026-10-22T06:55:42Z","timestamp":1792652142000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.9400711"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,10,21]]},"references-count":62,"alternative-id":["10.1002\/anie.9400711"],"URL":"https:\/\/doi.org\/10.1002\/anie.9400711","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,10,21]]},"assertion":[{"value":"2026-07-26","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-10-10","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-10-21","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e9400711"}}