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Replacing this chemistry with O\n                    <jats:sub>2<\/jats:sub>\n                    \u2013H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    interconversion offers a compelling alternative, because two\u2010electron (2e\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) oxygen electrocatalysis features intrinsically more reversible pathways and faster kinetics. Herein, fluorine\u2010doped graphene is established as a programmable electrocatalytic platform for O\n                    <jats:sub>2<\/jats:sub>\n                    \u2010H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    interconversion, where tailored sp\n                    <jats:sup>2<\/jats:sup>\n                    \u2010C\u2500F bonding acts as a precise electronic lever to regulate OOH* intermediate binding and thereby steer O\n                    <jats:sub>2<\/jats:sub>\n                    \u2013H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    redox selectivity and kinetics. By controlling fluorine incorporation, the local electronic environment of graphene is delicately engineered without sacrificing electrical conductivity. The optimized catalyst exhibits outstanding bifunctional activity for 2e\n                    <jats:sup>\u2212<\/jats:sup>\n                    oxygen reduction reaction (2e\n                    <jats:sup>\u2013<\/jats:sup>\n                    \u2010ORR) and peroxide oxidation reaction (POR), translating into rechargeable zinc\u2010based batteries with high power output and robust long\u2010term durability. Mechanistic studies reveal that sp\n                    <jats:sup>2<\/jats:sup>\n                    \u2010C\u2500F bonding induces localized electrostatic polarization at neighboring carbon sites, selectively stabilizing OOH* intermediates, lowering the kinetic barrier for 2e\n                    <jats:sup>\u2013<\/jats:sup>\n                    \u2010ORR, and concurrently facilitating POR while minimizing parasitic reactions. These findings demonstrate a fundamental structure\u2010property principle linking fluorine\u2010induced polarization with O\n                    <jats:sub>2<\/jats:sub>\n                    \u2013H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    redox kinetics, and position fluorinated carbon frameworks as a versatile foundation for next\u2010generation reversible energy storage.\n                  <\/jats:p>","DOI":"10.1002\/anie.9423554","type":"journal-article","created":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T15:28:52Z","timestamp":1790436532000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Tailored sp\n                    <sup>2<\/sup>\n                    \u2010C\u2500F Bonding for Reversible Oxygen\u2010Peroxide 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